Tris(1,10-phenanthroline-κ 2 N , N ′)iron(II) bis(1,1-dicyano-2-ethoxy-2-oxoethanide)

The title compound, [Fe(C 12 H 8 N 2 ) 3 ](C 6 H 5 N 2 O 2 ) 2 , consists of one [Fe(phen) 3 ] 2+ cation (phen = 1,10-phenanthroline) and two 1,1-dicyano-2-eth­oxy-2-oxoethanide anions. Five atoms of the anion are disordered over two positions [site occupancy = 0.521 (13) for the major component]. I...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-07, Vol.68 (7), p.m956-m956
Main Authors: Cai, Zhan-Mao, Zhan, Shu-Zhong
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:The title compound, [Fe(C 12 H 8 N 2 ) 3 ](C 6 H 5 N 2 O 2 ) 2 , consists of one [Fe(phen) 3 ] 2+ cation (phen = 1,10-phenanthroline) and two 1,1-dicyano-2-eth­oxy-2-oxoethanide anions. Five atoms of the anion are disordered over two positions [site occupancy = 0.521 (13) for the major component]. In the complex cation, the Fe II atom is coordinated by six N atoms from three phen ligands in a distorted octa­hedral geometry. Two intra­molecular C—H⋯N hydrogen bonds occur in the complex cation. The crystal structure is mainly stabilized by Coulombic inter­actions. Weak intermolecular C—H⋯N inter­actions are also observed.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812026967