Paired Electrolysis Enabled Cyanation of Diaryl Diselenides with KSCN Leading to Aryl Selenocyanates

The first example of paired electrolysis-enabled cyanation of diaryl diselenides, with KSCN as the green cyanating agent, has been developed. A broad range of aryl selenocyanates can be efficiently synthesized under chemical-oxidant- and additive-free, energy-saving and mild conditions.

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2023-02, Vol.28 (3), p.1397
Main Authors: He, Wei-Bao, Tang, Luo-Lin, Jiang, Jun, Li, Xiao, Xu, Xinhua, Yang, Tian-Bao, He, Wei-Min
Format: Article
Language:English
Subjects:
Aromatic compounds
aryl selenocyanates
Chemical properties
Chemical research
Chromatography
Communication
cyanation
Cyanides
diaryl diselenides
Efficiency
Electrodes
Electrolysis
Electrolytes
Energy conservation
Graphite
green chemistry
Oxidants
Oxidation
Oxidizing agents
paired electrolysis
Potassium compounds
Production processes
Selenides
Selenium
Selenium compounds
Solvents
Substitution reactions
Voltammetry
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Description
Summary:The first example of paired electrolysis-enabled cyanation of diaryl diselenides, with KSCN as the green cyanating agent, has been developed. A broad range of aryl selenocyanates can be efficiently synthesized under chemical-oxidant- and additive-free, energy-saving and mild conditions.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules28031397