Large-band-gap non-Dirac quantum spin Hall states and strong Rashba effect in functionalized thallene films

The quantum spin Hall state materials have recently attracted much attention owing to their potential applications in the design of spintronic devices. Based on density functional theory calculations and crystal field theory, we study electronic structures and topological properties of functionalize...

Full description

Saved in:
Bibliographic Details
Published in:Scientific reports 2023-09, Vol.13 (1), p.15966-15966, Article 15966
Main Authors: Liu, Xiaojuan, Li, Zhijian, Bao, Hairui, Yang, Zhongqin
Format: Article
Language:English
Subjects:
639/301
639/301/119
639/301/119/544
Electric fields
Electronic equipment
Graphene
Humanities and Social Sciences
Hydrogenation
multidisciplinary
Phase transitions
Physics
Science
Science (multidisciplinary)
Symmetry
Thallium
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The quantum spin Hall state materials have recently attracted much attention owing to their potential applications in the design of spintronic devices. Based on density functional theory calculations and crystal field theory, we study electronic structures and topological properties of functionalized thallene films. Two different hydrogenation styles (Tl 2 H and Tl 2 H 2 ) are considered, which can drastically vary the electronic and topological behaviors of the thallene. Due to the C 3v symmetry of the two systems, the p x and p y orbitals at the Γ point have the non-Dirac band degeneracy. With spin–orbit coupling (SOC), topological nontrivial band gaps can be generated, giving rise to non-Dirac quantum spin Hall states in the two thallium hydride films. The nontrivial band gap for the monolayer Tl 2 H is very large (855 meV) due to the large on-site SOC of Tl p x and p y orbitals. The band gap in Tl 2 H 2 is, however, small due to the band inversion between the Tl p x/y and p z orbitals. It is worth noting that both the Tl 2 H and Tl 2 H 2 monolayers exhibit strong Rashba spin splitting effects, especially for the monolayer Tl 2 H 2 (α R  = 2.52 eVÅ), rationalized well by the breaking of the structural inversion symmetry. The Rashba effect can be tuned sensitively by applying biaxial strain and external electric fields. Our findings provide an ideal platform for fabricating room-temperature spintronic and topological electronic devices.
ISSN:2045-2322
2045-2322
DOI:10.1038/s41598-023-43314-4