Tailoring topology and bio-interactions of triazine frameworks

The construction of covalent organic frameworks with special geometery and optical properties is of high interest, due to their unique physicochemical and biological properties. In this work, we report on a new method for the construction of triazine frameworks with defined topologies using coordina...

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Bibliographic Details
Published in:Scientific reports 2024-06, Vol.14 (1), p.14777-11, Article 14777
Main Authors: Bagheri, Sara, Adeli, Mohsen, Zabardasti, Abedin, Beyranvand, Siamak
Format: Article
Language:English
Subjects:
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Antibacterial activity
Biological activity
Biological properties
Biopolymers
Chemical reactions
Chemistry
Chloride
Cobalt
Construction
Enantiorecognition
Humanities and Social Sciences
Investigations
Mechanochemistry
Morphology
multidisciplinary
Nanomaterials
Optical activity
Optical properties
Polymers
Scanning electron microscopy
Science
Science (multidisciplinary)
Solvents
Topology
Triazine
Triazine frameworks
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Summary:The construction of covalent organic frameworks with special geometery and optical properties is of high interest, due to their unique physicochemical and biological properties. In this work, we report on a new method for the construction of triazine frameworks with defined topologies using coordination chemistry. Ball milling and wet chemical reactions between cyanuric chloride and melamine were directed in spatial arrangements and opposite optical activity. Cobalt was used as a directing agent to drive reactions into special morphologies, optical properties and biological activity. The enantiorecognition ability of triazine frameworks that was manifested in their activities against bacteria, demonstrated a new way for the construction of materials with specific interactions at biointerfaces.
ISSN:2045-2322
2045-2322
DOI:10.1038/s41598-024-64787-x