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Tailoring topology and bio-interactions of triazine frameworks
The construction of covalent organic frameworks with special geometery and optical properties is of high interest, due to their unique physicochemical and biological properties. In this work, we report on a new method for the construction of triazine frameworks with defined topologies using coordina...
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Published in: | Scientific reports 2024-06, Vol.14 (1), p.14777-11, Article 14777 |
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description | The construction of covalent organic frameworks with special geometery and optical properties is of high interest, due to their unique physicochemical and biological properties. In this work, we report on a new method for the construction of triazine frameworks with defined topologies using coordination chemistry. Ball milling and wet chemical reactions between cyanuric chloride and melamine were directed in spatial arrangements and opposite optical activity. Cobalt was used as a directing agent to drive reactions into special morphologies, optical properties and biological activity. The enantiorecognition ability of triazine frameworks that was manifested in their activities against bacteria, demonstrated a new way for the construction of materials with specific interactions at biointerfaces. |
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subjects | 639/638/298 639/638/403 639/638/455 Antibacterial activity Biological activity Biological properties Biopolymers Chemical reactions Chemistry Chloride Cobalt Construction Enantiorecognition Humanities and Social Sciences Investigations Mechanochemistry Morphology multidisciplinary Nanomaterials Optical activity Optical properties Polymers Scanning electron microscopy Science Science (multidisciplinary) Solvents Topology Triazine Triazine frameworks |
title | Tailoring topology and bio-interactions of triazine frameworks |
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