Versatility of the Templated Surface Assembly of Nanoparticles from Water-in-Oil Microemulsions in Equivalent Hybrid Nanostructured Films

Water-in-oil microemulsions, as stable colloidal dispersions from quasi-ternary mixtures, have been used in diverse applications, including nanoreactors for confined chemical processes. Their use as soft templates not only includes nanomaterial synthesis but also the interfacial assembly of nanopart...

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Published in:Nanomaterials (Basel, Switzerland) Switzerland), 2024-10, Vol.14 (21), p.1726
Main Authors: Fortes Martín, Rebeca, Rüstig, Sibylle, Bald, Ilko, Koetz, Joachim
Format: Article
Language:English
Subjects:
Acids
Aqueous solutions
Assembly
Chemical reactions
Chemical synthesis
Coatings
Colloid chemistry
Colloiding
Dispersions
Electron microscopes
electron microscopy
Equivalence
Ethanol
Evaporation
interfacial assembly
Liquid phases
Microemulsions
Microscopy
Nanomaterials
Nanoparticles
Nanostructure
nanostructures
Quantum dots
Scanning electron microscopy
self-assembly
Silicon wafers
Silver
Solvents
Spectroscopy
Surfactants
Thin films
Versatility
Water
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container_start_page 1726
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creator Fortes Martín, Rebeca
Rüstig, Sibylle
Bald, Ilko
Koetz, Joachim
description Water-in-oil microemulsions, as stable colloidal dispersions from quasi-ternary mixtures, have been used in diverse applications, including nanoreactors for confined chemical processes. Their use as soft templates not only includes nanomaterial synthesis but also the interfacial assembly of nanoparticles in hybrid nanostructures. Especially the hierarchical arrangement of different types of nanoparticles over a surface in filament networks constitutes an interesting bottom-up strategy for facile and tunable film coating. Herein, we demonstrate the versatility of this surface assembly from microemulsion dispersions. Transmission and Scanning Electron Microscopy, in addition to UV-Vis Transmittance Spectroscopy, proved the assembly tunability after solvent evaporation under different conditions: the nanostructured films can be formed over different surfaces, using different compositions of liquid phases, as well as with the incorporation of different nanoparticle materials while keeping equivalent surface functionalization. This offers the possibility of adapting different components and conditions for coating tuning on a larger scale with simple procedures.
doi_str_mv 10.3390/nano14211726
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subjects Acids
Aqueous solutions
Assembly
Chemical reactions
Chemical synthesis
Coatings
Colloid chemistry
Colloiding
Dispersions
Electron microscopes
electron microscopy
Equivalence
Ethanol
Evaporation
interfacial assembly
Liquid phases
Microemulsions
Microscopy
Nanomaterials
Nanoparticles
Nanostructure
nanostructures
Quantum dots
Scanning electron microscopy
self-assembly
Silicon wafers
Silver
Solvents
Spectroscopy
Surfactants
Thin films
Versatility
Water
title Versatility of the Templated Surface Assembly of Nanoparticles from Water-in-Oil Microemulsions in Equivalent Hybrid Nanostructured Films
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