Reactant-Induced Structural Evolution of Pt Catalysts Confined in Zeolite

Reactant-induced structural evolutions of heterogeneous metal catalysts are frequently observed in numerous catalytic systems, which can be associated with the formation or deactivation of active sites. In this work, we will show the structural transformation of subnanometer Pt clusters in pure-sili...

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Bibliographic Details
Published in:JACS Au 2024-02, Vol.4 (2), p.666-679
Main Authors: Li, Xiaoyu, Cheng, Jinling, Hou, Huaming, Meira, Debora M., Liu, Lichen
Format: Article
Language:English
Subjects:
clusters
CO oxidation
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
platinum
structural evolution
zeolite
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Summary:Reactant-induced structural evolutions of heterogeneous metal catalysts are frequently observed in numerous catalytic systems, which can be associated with the formation or deactivation of active sites. In this work, we will show the structural transformation of subnanometer Pt clusters in pure-silica MFI zeolite structure in the presence of CO, O2, and/or H2O and the catalytic consequences of the Pt-zeolite materials derived from various treatment conditions. By applying the appropriate pretreatment under a reactant atmosphere, we can precisely modulate the size distribution of Pt species spanning from single Pt atoms to small Pt nanoparticles (1–5 nm) in the zeolite matrix, resulting in the desirably active and stable Pt species for CO oxidation. We also show the incorporation of Fe into the zeolite framework greatly promotes the stability of Pt species against undesired sintering under harsh conditions (up to 650 °C in the presence of CO, O2, and moisture).
ISSN:2691-3704
2691-3704
DOI:10.1021/jacsau.3c00732