Calculation of Resonance Fluorescence Scattering Cross Sections of Metal Particles in the Middle and Upper Atmosphere and Comparison of Their Detectability

• Published in: Atmosphere 2023-08, Vol.14 (8), p.1283
• Main Authors: Wang, Kexin, Wang, Zelong, Wu, Yuxuan, Xia, Yuan, Xun, Yuchang, Wu, Fuju, Jiao, Jing, Du, Lifang
• Format: Article
• Language: English
• Subjects: Absorption cross sections; Atmosphere; Atmosphere, Upper; atmospheric metal layer; Atoms & subatomic particles; Backscatter; Backscattering; Composition; Data analysis; Data processing; detectability; effective backscattering cross section; Environmental aspects; Fluorescence; Frequency locking; Heavy metals; Ions; Iron; Isotopes; Lasers; Lidar; Lidar observations; Mathematical analysis; Metal particles; Metals; Optical properties; Particles; Remote sensing; Resonance; Resonance fluorescence; Resonance scattering; Scattering (Physics); Scattering cross sections; Sodium; Uncertainty; Upper atmosphere
• ISSN: 2073-4433; 2073-4433
• DOI: 10.3390/atmos14081283

Resonance fluorescence scattering is the physical mechanism with which lidar detects atmospheric metal layers. The resonance fluorescence scattering cross section is an important parameter for lidar data processing. In this work, the resonance fluorescence backscattering cross sections of most detectable metal atoms and ions in the atmosphere were calculated. The calculated maximum backscattering cross section of Na at the D2 line is 7.38 × 10−17 m2/sr; K at the D1 line is 7.37 × 10−17 m2/sr; Fe at the 372 nm line is 7.53 × 10−18 m2/sr; Fe at the 374 nm line is 6.98 × 10−18 m2/sr; Fe at the 386 nm line is 3.75 × 10−18 m2/sr; Ni at the 337 nm line is 4.05 × 10−18 m2/sr; and Ni at the 341 nm line is 2.05 × 10−17 m2/sr; Ca is 3.06 × 10−16 m2/sr; Ca+ is 1.12 × 10−16 m2/sr. The influence of the laser linewidth on the effective scattering cross section was discussed. If the laser linewidth is lower than 2 GHz to detect Na, the laser center frequency locked at the D2a line is a better option than the D2 line in order to obtain greater signals. If an unlocked lidar is used to detect Na, the frequency at D2a should be used as the laser center frequency when the effective scattering cross section of Na was calculated, because the absorption cross section of Na atom has two local maxima. This work proposes a quantifiable comparative method for assessing the observation difficulty of different metal particles by comparing their relative uncertainties in lidar observation. It is assumed that under the same observation conditions, the detectability of different metal atoms and ions is compared. Using Na as a basis for comparison, the relative uncertainty of Ni at 337 nm is the highest, about a factor of 21 larger than that of Na, indicating that it is the most difficult to be detected. The purpose of this work is to present a quantifiable comparison method for the detection difficulty of the metal particles by lidar in the middle and upper atmosphere, which has great significance for the design of the lidar system.