CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n

The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with...

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Bibliographic Details
Published in:Journal of engineering studies and research 2020-07, Vol.26 (3)
Main Authors: MODOU SARR, MOUHAMADOU BIRAME DIOP, AMINATA DIASSE-SARR, AI WANG, ULLRICH ENGLERT
Format: Article
Language:English
Subjects:
infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin
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Summary:The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with Z = 4, a = 14.7091 (18) Å, b = 15.4133 (19) Å, c = 14.7639 (18) Å, β = 94.242 (2)° and V = 3338.0 (7) Å3. The structure consists of an infinite chain propagating along the crystallographic a-axis direction with bidentate formate anions. The O2SnC3 core is organized into a trans-trigonal bipyramidal like-arrangement.
ISSN:2068-7559
2344-4932