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Surface Nanotexturing of Boron-Doped Diamond Films by Ultrashort Laser Pulses
Polycrystalline boron-doped diamond (BDD) films were surface nanotextured by femtosecond pulsed laser irradiation (100 fs duration, 800 nm wavelength, 1.44 J cm single pulse fluence) to analyse the evolution of induced alterations on the surface morphology and structural properties. The aim was to i...
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Published in: | Micromachines (Basel) 2023-02, Vol.14 (2), p.389 |
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description | Polycrystalline boron-doped diamond (BDD) films were surface nanotextured by femtosecond pulsed laser irradiation (100 fs duration, 800 nm wavelength, 1.44 J cm
single pulse fluence) to analyse the evolution of induced alterations on the surface morphology and structural properties. The aim was to identify the occurrence of laser-induced periodic surface structures (LIPSS) as a function of the number of pulses released on the unit area. Micro-Raman spectroscopy pointed out an increase in the graphite surface content of the films following the laser irradiation due to the formation of ordered carbon sites with respect to the pristine sample. SEM and AFM surface morphology studies allowed the determination of two different types of surface patterning: narrow but highly irregular ripples without a definite spatial periodicity or long-range order for irradiations with relatively low accumulated fluences ( |
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single pulse fluence) to analyse the evolution of induced alterations on the surface morphology and structural properties. The aim was to identify the occurrence of laser-induced periodic surface structures (LIPSS) as a function of the number of pulses released on the unit area. Micro-Raman spectroscopy pointed out an increase in the graphite surface content of the films following the laser irradiation due to the formation of ordered carbon sites with respect to the pristine sample. SEM and AFM surface morphology studies allowed the determination of two different types of surface patterning: narrow but highly irregular ripples without a definite spatial periodicity or long-range order for irradiations with relatively low accumulated fluences (<14.4 J cm
) and coarse but highly regular LIPSS with a spatial periodicity of approximately 630 nm ± 30 nm for higher fluences up to 230.4 J cm
.</description><identifier>ISSN: 2072-666X</identifier><identifier>EISSN: 2072-666X</identifier><identifier>DOI: 10.3390/mi14020389</identifier><identifier>PMID: 36838089</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Ablation ; Boron ; boron-doped diamond ; Chemical reactions ; Chemical vapor deposition ; Diamond films ; Electrochemical reactions ; Energy ; Femtosecond pulsed lasers ; Fluence ; Irradiation ; laser texturing ; Lasers ; LIPSS ; Long range order ; Microelectromechanical systems ; Morphology ; Radiation ; Raman spectroscopy ; ripples ; Scanning electron microscopy ; Silicon wafers ; Software ; surface functionalization</subject><ispartof>Micromachines (Basel), 2023-02, Vol.14 (2), p.389</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2023 by the authors. 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c511t-203b35d6903ea15d5596fc0490193b3f5f87f7507bcf5285f1e3d96eea0507183</citedby><cites>FETCH-LOGICAL-c511t-203b35d6903ea15d5596fc0490193b3f5f87f7507bcf5285f1e3d96eea0507183</cites><orcidid>0000-0002-5440-8154 ; 0000-0001-8278-4707 ; 0000-0002-4291-6477 ; 0000-0002-2081-1164 ; 0000-0002-6551-0883 ; 0000-0001-7509-3318 ; 0000-0001-5116-3908 ; 0000-0002-6079-0900</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2779513388/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2779513388?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36838089$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mastellone, Matteo</creatorcontrib><creatorcontrib>Bolli, Eleonora</creatorcontrib><creatorcontrib>Valentini, Veronica</creatorcontrib><creatorcontrib>Orlando, Stefano</creatorcontrib><creatorcontrib>Lettino, Antonio</creatorcontrib><creatorcontrib>Polini, Riccardo</creatorcontrib><creatorcontrib>Buijnsters, Josephus Gerardus</creatorcontrib><creatorcontrib>Bellucci, Alessandro</creatorcontrib><creatorcontrib>Trucchi, Daniele Maria</creatorcontrib><title>Surface Nanotexturing of Boron-Doped Diamond Films by Ultrashort Laser Pulses</title><title>Micromachines (Basel)</title><addtitle>Micromachines (Basel)</addtitle><description>Polycrystalline boron-doped diamond (BDD) films were surface nanotextured by femtosecond pulsed laser irradiation (100 fs duration, 800 nm wavelength, 1.44 J cm
single pulse fluence) to analyse the evolution of induced alterations on the surface morphology and structural properties. The aim was to identify the occurrence of laser-induced periodic surface structures (LIPSS) as a function of the number of pulses released on the unit area. Micro-Raman spectroscopy pointed out an increase in the graphite surface content of the films following the laser irradiation due to the formation of ordered carbon sites with respect to the pristine sample. SEM and AFM surface morphology studies allowed the determination of two different types of surface patterning: narrow but highly irregular ripples without a definite spatial periodicity or long-range order for irradiations with relatively low accumulated fluences (<14.4 J cm
) and coarse but highly regular LIPSS with a spatial periodicity of approximately 630 nm ± 30 nm for higher fluences up to 230.4 J cm
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single pulse fluence) to analyse the evolution of induced alterations on the surface morphology and structural properties. The aim was to identify the occurrence of laser-induced periodic surface structures (LIPSS) as a function of the number of pulses released on the unit area. Micro-Raman spectroscopy pointed out an increase in the graphite surface content of the films following the laser irradiation due to the formation of ordered carbon sites with respect to the pristine sample. SEM and AFM surface morphology studies allowed the determination of two different types of surface patterning: narrow but highly irregular ripples without a definite spatial periodicity or long-range order for irradiations with relatively low accumulated fluences (<14.4 J cm
) and coarse but highly regular LIPSS with a spatial periodicity of approximately 630 nm ± 30 nm for higher fluences up to 230.4 J cm
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subjects | Ablation Boron boron-doped diamond Chemical reactions Chemical vapor deposition Diamond films Electrochemical reactions Energy Femtosecond pulsed lasers Fluence Irradiation laser texturing Lasers LIPSS Long range order Microelectromechanical systems Morphology Radiation Raman spectroscopy ripples Scanning electron microscopy Silicon wafers Software surface functionalization |
title | Surface Nanotexturing of Boron-Doped Diamond Films by Ultrashort Laser Pulses |
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