Fabrication of Si Nanoparticles@Carbon Fibers Composites from Natural Nanoclay as an Advanced Lithium-Ion Battery Flexible Anode

• Published in: Minerals (Basel) 2018-05, Vol.8 (5), p.180
• Main Authors: Liu, Sainan, Zhang, Qiang, Yang, Huaming, Mu, Dawei, Pan, Anqiang, Liang, Shuquan
• Format: Article
• Language: English
• Subjects: Anode effect; Anodes; Batteries; Carbon; Carbon fiber reinforced plastics; Carbon fibers; Chemical reduction; Clay; Clay minerals; Commercialization; Composite materials; Current density; Cycles; Electrochemical analysis; Electrochemistry; Electrodes; Fabrication; Fibers; flexible anode; halloysite; Lithium; Lithium-ion batteries; lithium-ion battery; Marketing; Minerals; Nanoparticles; Rechargeable batteries; Silicon; Specific capacity
• ISSN: 2075-163X; 2075-163X
• DOI: 10.3390/min8050180

In this paper, a cost-effective strategy for fabricating silicon-carbon composites was designed to further improve the electrochemical performance and commercialization prospects of Si anodes for lithium-ion batteries (LIBs). Silicon-carbon fibers (CFs) were prepared by loading Si nanoparticles (SiNPs) on interconnected carbon fibers via an electrospinning technique (SiNPs@CFs). The Si nanoparticles were obtained by the reduction reaction of natural clay minerals. As a flexible anode for LIBs, the SiNPs@CFs anode demonstrated a reversible capacity of 1238.1 mAh•g−1 and a capacity retention of 77% after 300 cycles (in contrast to the second cycle) at a current density of 0.5 A•g−1. With a higher current density of 5.0 A•g−1, the electrode showed a specific capacity of 528.3 mAh•g−1 after 1000 cycles and exhibited a superior rate capability compared to Si nanoparticles. The excellent electrochemical properties were attributed to the construction of flexible electrodes and the composite comprising carbon fibers, which lessened the volume expansion and improved the conductivity of the system.