Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II)

The single crystal structure of cis-dichlorobis(triphenyphosphite) platinum(II), [PtCl2(P(OPh)3)2] has been determined. This complex crystallises in the orthorhombic space group, P212121 with cell constant, a=10.4135(13), b=14.0635(16), c=23.505(3) Ǻ and v=3448.3(7) Ǻ 3. The Pt-Cl1 and Pt-Cl2 distan...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2001-08, Vol.6 (9), p.777-783
Main Authors: Sabounchei, Seyyed Javad, Naghipour, Ali
Format: Article
Language:English
Subjects:
Crystal structure
Data collection
Ligands
Molecular structure
Platinum complex
Triphenylphosphite ligands
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Summary:The single crystal structure of cis-dichlorobis(triphenyphosphite) platinum(II), [PtCl2(P(OPh)3)2] has been determined. This complex crystallises in the orthorhombic space group, P212121 with cell constant, a=10.4135(13), b=14.0635(16), c=23.505(3) Ǻ and v=3448.3(7) Ǻ 3. The Pt-Cl1 and Pt-Cl2 distances are 2.3390(10) Ǻ and 2.3256 Ǻ, which are longer than Pt-P1 and Pt-P2 with 2.1985(12) Ǻ and 2.1998(10) Ǻ respectively. These data together with bond angles suggest a distorted square planar geometry for this complex with two chlorine ligands in a cis configuration.
ISSN:1420-3049
1420-3049
DOI:10.3390/60900777