A high density and low sensitivity carrier explosive promising to replace TNT: 3-Bromo-5-fluoro-2,4,6-trinitroanisole

• Published in: Energetic materials frontiers 2024-06, Vol.5 (2), p.131-140
• Main Authors: Wang, Yi, Song, Xiao-lan, Yu, Zhi-hong, Song, Dan, An, Chong-wei, Li, Feng-sheng
• Format: Article
• Language: English
• Subjects: BFTNAN; Detonation performance; Melt-cast explosives; Sensitivities; Thermolysis
• ISSN: 2666-6472; 2666-6472
• DOI: 10.1016/j.enmf.2024.06.003

To address the issues of high saturated vapor pressure, high toxicity, and high viscosity of TNT, this article used a chemical method to synthesize a new carrier explosive BFTNAN. The prepared samples were characterized using scanning electron microscope(SEM), energy spectrum(EDS), x-ray diffraction(XRD), infrared spectrum(IR), x-ray photoelectron spectroscopy(XPS), nuclear magnetic resonance, and elemental analysis techniques. The enthalpy of formation of BFTNAN was measured using a specialized calorimeter that is specially used in testing of explosives and powders. The thermal decomposition performance of BFTNAN was tested by DSC technology. Meanwhile, the mechanical sensitivity, thermal sensitivity, and detonation performance of BFTNAN based melt-cast explosive was also tested. The results of characterizations showed that the prepared sample was indeed BFTNAN. The enthalpy of formation of BFTNAN was determined as ΔHf,BFTNAN = −72.6 kJ·mol−1. At a heating rate of 20 °C·min−1, the thermal decomposition peak of BFTNAN is at TP = 250.6 °C, and the activation energy is EK = 80 kJ·mol−1, which is closed to the Tp and EK values of TNT. This indicates that BFTNAN is a relatively easy to decompose explosive, but the decomposition rate is not fast. The critical temperature for thermal explosion of BFTNAN reached Tb = 216 °C, which is also closed to the Tb value of TNT. The impact and friction sensitivity of BFTNAN were lower than those of TNT, which was closed to those of DNAN. The thermal sensitivity of BFTNAN is lower than TNT. The detonation velocity and heat of explosion of BFTNAN based melt-cast explosive were distinctly higher than those of TNT based explosive. Especially, BFTNAN based melt-cast explosive were of the advantages in chemical energy storage, work capacity, brisance, and ability of acceleration metals. The innovation of this article is the synthesis of a low melting point, low sensitivity, and high-energy explosive BFTNAN for the first time. This type of explosive has the potential to replace TNT as a liquid-phase carrier for molten explosives. The properitesn were tested and calculated. [Display omitted] •A new carrier explosive BFTNAN was synthesized for the first time.•The detonation velocity and heat of explosion of BFTNAN are higher than those of TNT and DNAN. The impact and friction sensitivity of BFTNAN are lower than TNT and are closed to those of DNAN.•The enthalpy of formation of BFTNAN is determined as ΔHf,BFTNAN = −72.6 kJ/mol.