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(4,4′-Dimethyl-2,2′-bipyridine-κ 2 N , N ′)(dimethylformamide-κ O )diiodidocadmium
In the title compound, [CdI2(C12H12N2)(C3H7NO)], the CdII cation is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethylformamide ligand and two I− anions. &am...
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Published in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-12, Vol.68 (12), p.m1495-m1495 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | In the title compound, [CdI2(C12H12N2)(C3H7NO)], the CdII cation is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethylformamide ligand and two I− anions. π–π stacking between pyridine rings of adjacent molecules [centroid–centroid distance = 3.666 (3) and 3.709 (4) Å] stabilizes the three-dimensional structure |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812046648 |