2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide

The title molecule, C 9 H 7 ClN 4 OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H...O and N—H...N hydrogen bonds form S (6) and S (5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dim...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-01, Vol.70 (1), p.o64-o65
Main Authors: Bittencourt, Viviane Conceição Duarte de, Vicenti, Juliano Rosa de Menezes, Velasques, Jecika Maciel, Zambiazi, Priscilla Jussiane, Gervini, Vanessa Carratu
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The title molecule, C 9 H 7 ClN 4 OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H...O and N—H...N hydrogen bonds form S (6) and S (5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers through pairs of co-operative N—H...Cl interactions. These dimers are connected along the b axis by N—H...O and N—H...S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking interactions [centroid–centroid distance = 3.849 (2) Å].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813033369