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Dichlorido(1-{(E)-[phenyl(pyridin-2-yl- #954;N)methylidene]amino- #954;N}pyrrolidin-2-one- #954;O)copper(II) monohydrate
The CuII atom in the title compound, [CuCl2(C16H15N3O)]·H2O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 &...
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Published in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-09, Vol.68 (9), p.m1181-m1181 |
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container_title | Acta crystallographica. Section E, Structure reports online |
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creator | Roji J. Kunnath M.R. Prathapachandra Kurup Seik Weng Ng |
description | The CuII atom in the title compound, [CuCl2(C16H15N3O)]·H2O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water molecules, the interaction generating a centrosymmetric dimer through a cyclic R42(8) association. |
doi_str_mv | 10.1107/S1600536812035398 |
format | article |
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It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water molecules, the interaction generating a centrosymmetric dimer through a cyclic R42(8) association.]]></description><issn>1600-5368</issn><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNqtjMtKxDAYhYMoOF4ewN2Am3YRTZq00-JSR-xGF7oTKWn6j82Q5g9pFwbx3Z2RCj6Aq3P4zoWQC86uOGer62deMJaLouQZE7moygOy2CO6Z4d__DE5GcctY7xYZXxBPu6M7i0G02HC6WeyTumr78FFm_i4o8bRjEZLl5dVLm8e0wGmPlrTgYM3NRiHv8nXrh7Qzgt0MAdPqUbvISR1nS4HdNjHLqgJzsjRRtkRzmc9JfX9-uX2gXaoto0PZlAhNqhM8wMwvDcqTEZbaHSZCbEpVFuWTOpKtEJypSsJHKSSeSv-8-sb1khqCw</recordid><startdate>20120901</startdate><enddate>20120901</enddate><creator>Roji J. Kunnath</creator><creator>M.R. 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Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Roji J. Kunnath</au><au>M.R. Prathapachandra Kurup</au><au>Seik Weng Ng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dichlorido(1-{(E)-[phenyl(pyridin-2-yl- #954;N)methylidene]amino- #954;N}pyrrolidin-2-one- #954;O)copper(II) monohydrate</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2012-09-01</date><risdate>2012</risdate><volume>68</volume><issue>9</issue><spage>m1181</spage><epage>m1181</epage><pages>m1181-m1181</pages><issn>1600-5368</issn><eissn>1600-5368</eissn><abstract><![CDATA[The CuII atom in the title compound, [CuCl2(C16H15N3O)]·H2O, is N,N′,O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water molecules, the interaction generating a centrosymmetric dimer through a cyclic R42(8) association.]]></abstract><pub>International Union of Crystallography</pub><doi>10.1107/S1600536812035398</doi><oa>free_for_read</oa></addata></record> |
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title | Dichlorido(1-{(E)-[phenyl(pyridin-2-yl- #954;N)methylidene]amino- #954;N}pyrrolidin-2-one- #954;O)copper(II) monohydrate |
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