Influence of As-N Interstitial Complexes on Strain Generated in GaAsN Epilayers Grown by AP-MOVPE

• Published in: Energies (Basel) 2022-05, Vol.15 (9), p.3036
• Main Authors: Ściana, Beata, Dawidowski, Wojciech, Radziewicz, Damian, Jadczak, Joanna, López-Escalante, Mari Cruz, González de la Cruz, Victor, Gabás, Mercedes
• Format: Article
• Language: English
• Subjects: Alloying effects; AP-MOVPE; Arsenic; dilute nitrides; Gallium arsenide; Heterostructures; HRXRD; III-V semiconductors; Interstitial defects; Interstitials; Metalorganic chemical vapor deposition; Nitrogen; Nitrogen atoms; nitrogen interstitial complexes; Photoelectron spectroscopy; Photoelectrons; Raman spectroscopy; Spectroscopy; Spectrum analysis; Temperature; Thickness; Vapor phase epitaxy; Vapor phases; X ray photoelectron spectroscopy; X-ray diffraction; XPS
• ISSN: 1996-1073; 1996-1073
• DOI: 10.3390/en15093036

This work presents an investigation of the fully strained GaAsN/GaAs heterostructures obtained by atmospheric pressure metalorganic vapor phase epitaxy, focusing on the analysis of the strain generated in the GaAsN epilayers and its correlation with the formation of split interstitial complexes (N-As)As. We analyzed strained GaAsN epilayers with nitrogen contents and thicknesses varying from 0.93 to 1.81% and 65 to 130 nm, respectively. The composition and thickness were determined by high resolution X-ray diffraction, and the strain was determined by Raman spectroscopy, while the N-bonding configurations were determined by X-ray photoelectron spectroscopy. We found that the strain generated in the GaAsN epilayers is mainly caused by a lattice mismatch with the GaAs substrate. This macroscopic strain is independent of the amount of (N-As)As interstitial defects, while the local strain, induced by an alloying effect, tends to decrease with an increasing ratio of (N-As)As interstitial defects to substitutional nitrogen atoms incorporated into an arsenic sublattice—NAs. Here, we show experimentally, for the first time, a correlation between the strain in the GaAsN epilayers, caused by an alloying effect determined by Raman spectroscopy, and the (N-As)As/NAs ratio estimated by the XPS method. We found out that the (N-As)As interstitials compensate the local strain resulting from the presence of N in the GaAs matrix, if their amount does not exceed ~65% of the substitutional introduced nitrogen NAs.