Chitosan/magnetic biochar composite with enhanced reusability: Synergistic effect of functional groups and multilayer structure

• Published in: Arabian journal of chemistry 2024-05, Vol.17 (5), p.105746, Article 105746
• Main Authors: Yu, Yongbo, Liu, Wanting, Zhang, Yinuo, Zhang, Bolun, Jin, Yiping, Chen, Siji, Tang, Shanshan, Su, Yingjie, Yu, Xiaoxiao, Chen, Guang
• Format: Article
• Language: English
• Subjects: Chitosan; Cr(VI) removal; Crosslinking; Magnetic biochar; Reusability
• ISSN: 1878-5352; 1878-5379
• DOI: 10.1016/j.arabjc.2024.105746

Heavy metals in water bodies pose a significant threat to both ecology and human well-being. Therefore, the development of green and sustainable adsorbents for water remediation is essential. This study presents a crosslinked chitosan composite structure with multiple layers, which was generated by adjusting the ratio of chitosan to wheat straw–derived magnetic biochar in the composite. The adsorption behavior of the composite under different conditions was revealed by varying the Cr(VI) concentration, pH, and temperature. The composite exhibited a maximum adsorption of 121.8 mg g−1 for Cr(VI) in water, which was 11.9 times higher than that of magnetic biochar. It maintained a residual performance of 78.6 % after seven cycles, higher than most chitosan-based composites. The reusability was improved via hydrochloric acid protonation of functional groups and layer-by-layer exposure of the composite structure. This study provides new insights into the application of composites derived from chitosan and wheat straw, an agricultural waste, as sustainable adsorbents.