New Acidic Precursor and Acetone-Based Solvent for Fast Perovskite Processing via Proton-Exchange Reaction with Methylamine

A new solvent system for PbI based on HI solution in acetone with a low boiling point is proposed. High solubility of PbI is caused by the formation of iodoplumbate complexes, and reaches a concentration of 1.6 M. Upon its crystallization metastable solvate phases PbI ∙HI∙n{(CH ) CO} are formed. The...

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Published in:Molecules (Basel, Switzerland) Switzerland), 2020-04, Vol.25 (8), p.1856
Main Authors: Fateev, Sergey A, Marchenko, Ekaterina I, Petrov, Andrey A, Goodilin, Eugene A, Tarasov, Alexey B
Format: Article
Language:English
Subjects:
Acetone
Acetone - chemistry
Acids
Aqueous solutions
Boiling points
Calcium Compounds - chemistry
Communication
Crystallization
Decomposition
hybrid perovskites
lead halide perovskites
lead precursor
Methylamine
Methylamines - chemistry
Oxides - chemistry
perovskite solar cells
Perovskites
Protons
Solubility
Solvents
Solvents - chemistry
Spectrum Analysis
Spin coating
Thin films
Titanium - chemistry
Viscosity
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cited_by cdi_FETCH-LOGICAL-c493t-88fb6d4f36d24c81a56f3ad31bf1db013c545656fd307f71068df795dede0c093
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creator Fateev, Sergey A
Marchenko, Ekaterina I
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Tarasov, Alexey B
description A new solvent system for PbI based on HI solution in acetone with a low boiling point is proposed. High solubility of PbI is caused by the formation of iodoplumbate complexes, and reaches a concentration of 1.6 M. Upon its crystallization metastable solvate phases PbI ∙HI∙n{(CH ) CO} are formed. The latter allows for their easy deposition on substrates in a form of smooth and uniform thin films by spin-coating. Through a fast acid-base reaction with a gaseous amine, the films of the intermediate phase can be completely converted to single-phase perovskite films. The developed method allows one to form smooth perovskite films with high crystallinity with a thickness up to 1 μm. Due to easy and fast processing, the developed method can be promising for perovskite technology upscaling.
doi_str_mv 10.3390/molecules25081856
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subjects Acetone
Acetone - chemistry
Acids
Aqueous solutions
Boiling points
Calcium Compounds - chemistry
Communication
Crystallization
Decomposition
hybrid perovskites
lead halide perovskites
lead precursor
Methylamine
Methylamines - chemistry
Oxides - chemistry
perovskite solar cells
Perovskites
Protons
Solubility
Solvents
Solvents - chemistry
Spectrum Analysis
Spin coating
Thin films
Titanium - chemistry
Viscosity
title New Acidic Precursor and Acetone-Based Solvent for Fast Perovskite Processing via Proton-Exchange Reaction with Methylamine
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