Functionalization of cellulose fibers and paper with lanthanide-based luminescent core/shell nanoparticles providing 3-level protection for advanced anti-counterfeiting purposes

• Published in: Materials & design 2022-06, Vol.218, p.110684, Article 110684
• Main Authors: Szczeszak, Agata, Skwierczyńska, Małgorzata, Przybylska, Dominika, Runowski, Marcin, Śmiechowicz, Emilia, Erdman, Aleksandra, Ivashchenko, Olena, Grzyb, Tomasz, Kulpiński, Piotr, Olejnik, Konrad
• Format: Article
• Language: English
• Subjects: Anti-Stokes emission; Functional materials; Lanthanide ions; Luminescence; Luminescent paper & cellulose fibres; Surface modification
• ISSN: 0264-1275; 1873-4197
• DOI: 10.1016/j.matdes.2022.110684

[Display omitted] •Lanthanide-doped core@shell nanoparticles for luminescent cellulose fibers production.•Dual-range excitation of luminescent materials with 975 and 1532 nm laser radiation.•Luminescent fibers as anti-counterfeiting agents for documents, clothes and valuable products.•‘3-level’ protection system resulting from a unique optical activity of the nanoparticles. The increasingly wide-spreading falsification of documents, clothing, and packaging has a negative impact on every aspect of the global markets. Therefore, the development of high-quality strategies for materials protection has become a big challenge. Thus, this work presents novel anti-counterfeiting lyocell fibres, exhibiting bright green or yellowish up-conversion emission upon dual-range excitation, using either 975-nm or 1532-nm NIR laser radiation. The up-converting cellulose fibers were prepared by introducing lanthanide-doped core@shell nanoparticles β-NaYF4: Yb3+, Er3+@β-NaYF4 into the cellulose matrix. The spinning process of fibres was based on N-methylmorpholine N-oxide method, environmentally friendly because of the reusable reagents used. The prepared fibres were incorporated into the paper mass, forming a luminescent paper as a proof of concept for the multi-modal protection of documents. The luminescent fibres have considerable application potential as anti-counterfeiting composite materials with excellent performance, which are very difficult to imitate or copy, providing a very high level of security.