Reproducible long-term cycling data of Al2O3 coated LiNi0.70Co0.15Mn0.15O2 cathodes for lithium-ion batteries

LiNi x Co y Mn 1- x - y O 2 (NCM) based cathodes for Li-ion batteries (LIBs) are of great interest due to their higher energy density and lower costs compared to conventional LiCoO 2 based cathodes. However, NCM based cathodes suffer from instabilities of the cathode-electrolyte interface resulting...

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Bibliographic Details
Published in:Scientific data 2022-03, Vol.9 (1), p.127-127, Article 127
Main Authors: Negi, Rajendra S., Elm, Matthias T.
Format: Article
Language:English
Subjects:
639/301/299/161/891
639/4077/4079/891
Aluminum oxide
Cathodes
Coatings
Data Descriptor
Humanities and Social Sciences
Lithium
multidisciplinary
Protective coatings
Science
Science (multidisciplinary)
Spectroscopy
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Summary:LiNi x Co y Mn 1- x - y O 2 (NCM) based cathodes for Li-ion batteries (LIBs) are of great interest due to their higher energy density and lower costs compared to conventional LiCoO 2 based cathodes. However, NCM based cathodes suffer from instabilities of the cathode-electrolyte interface resulting in faster capacity fading during long-term cycling. Different NCM compositions along with different coatings have been developed to protect the interface. However, a detailed understanding why and how coatings work is still missing. Up to now, no state-of-the-art NCM or coating material have been agreed upon yet, making it difficult to benchmark the performance of the coating material. Undefined standards complicate the use of experimentally produced data for model-based studies, which are a key element in assessing the beneficial effect of coatings. In this work, we therefore describe reproducible long-term cycling data of NCM based cathodes with and without an Al 2 O 3 based coating. The data set is provided to be used for parameter fitting and/or as training data to encourage the simulation of the performance of LIBs in model-based approaches. Measurement(s) specific discharge capacity • electrochemical-induced impedance spectroscopy Technology Type(s) battery cycler • potentiostat
ISSN:2052-4463
2052-4463
DOI:10.1038/s41597-022-01217-5