Sustainable Engineered Designs and Manufacturing of Waste Derived Graphenes Reinforced Polypropylene Composite for Automotive Interior Parts

• Published in: ACS omega 2024-08, Vol.9 (32), p.34530-34543
• Main Authors: Baskan-Bayrak, Havva, Yahyapour, Ramisa, Yagci, Yavuz Emre, Saner Okan, Burcu
• Format: Article
• Language: English
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.4c02596

The automotive sector is actively pursuing a lightweighting strategy as a means to urgently decrease greenhouse gas emissions, which are a significant driver of climate change. The development of lightweight composite structures has been identified as crucial for enhancing part performance while mitigating negative environmental impacts and adopting energy-efficient manufacturing methods. This comprehensive study aimed to decrease the main reinforcement content of talc in commercial compounds while integrating graphene derived from waste polypropylene (PP) grown on talc and graphene nanoplatelet obtained from waste tires by upcycling processes into the PP compound. The entire value chain of interior automotive part production, from compound development and scaling up with a high-shear mixer, to injection molding of the part and performance tests, was investigated with a focus on sustainability considerations. The successful integration of 4 wt % micron talc, together with 1 wt % graphene nanoparticles and 1 wt % hybrid additive into the blended HomoPP/CopoPP matrix resulted in a 10% weight reduction compared to the conventional part. Moreover, significant improvements in flexural and tensile strength were observed, with enhancements of 52 and 38%, respectively. The uniform dispersion of additives and improved interfacial adhesion between the PP matrix and additives facilitated efficient stress transfer, contributing to enhanced mechanical properties. Furthermore, a systematic life cycle assessment study demonstrated the positive impact of waste PP incorporation on CO2 reduction, achieving a remarkable 95% reduction compared to virgin PP. The developed compound also demonstrated favorable processability and flow properties, supporting its potential for mass production. Overall, this study presents a sustainable and effective approach for lightweight automotive interior part production using a synergistically designed PP compound meeting the requirements of the automotive industry.