Pd-catalyzed carbonyl insertion coupling reactions of a hypervalent iodoheterocycle with alcohols and amines

The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2005-01, Vol.10 (1), p.238-243
Main Authors: Luo, Shengj-Jun, Ma, Yong-Xiang, Liang, Yong-Min
Format: Article
Language:English
Subjects:
Alcohol
Alcohols - chemical synthesis
Alcohols - chemistry
amides
Amines - chemical synthesis
Amines - chemistry
Carbon - chemistry
carbonyl insertion
Catalysis - drug effects
Cross-coupling
esters
Heterocyclic Compounds - chemical synthesis
Heterocyclic Compounds - chemistry
hypervalent iodoheterocycle
Iodine Compounds - chemical synthesis
Iodine Compounds - chemistry
Models, Biological
Palladium
Palladium - pharmacology
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Description
Summary:The palladium-catalyzed cross-coupling carbonyl insertion reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e]iodinium iodide (1) and alcohols or amines 2 is described. Some new amides and esters 3 containing an active iodo functional group have been prepared in 65-91% yields.
ISSN:1420-3049
1420-3049
DOI:10.3390/10010238