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Unexpected behaviors in molecular transport through size-controlled nanochannels down to the ultra-nanoscale

Ionic transport through nanofluidic systems is a problem of fundamental interest in transport physics and has broad relevance in desalination, fuel cells, batteries, filtration, and drug delivery. When the dimension of the fluidic system approaches the size of molecules in solution, fluid properties...

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Bibliographic Details
Published in:Nature communications 2018-04, Vol.9 (1), p.1682-10, Article 1682
Main Authors: Bruno, Giacomo, Di Trani, Nicola, Hood, R. Lyle, Zabre, Erika, Filgueira, Carly Sue, Canavese, Giancarlo, Jain, Priya, Smith, Zachary, Demarchi, Danilo, Hosali, Sharath, Pimpinelli, Alberto, Ferrari, Mauro, Grattoni, Alessandro
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Language:English
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Summary:Ionic transport through nanofluidic systems is a problem of fundamental interest in transport physics and has broad relevance in desalination, fuel cells, batteries, filtration, and drug delivery. When the dimension of the fluidic system approaches the size of molecules in solution, fluid properties are not homogeneous and a departure in behavior is observed with respect to continuum-based theories. Here we present a systematic study of the transport of charged and neutral small molecules in an ideal nanofluidic platform with precise channels from the sub-microscale to the ultra-nanoscale (
ISSN:2041-1723
2041-1723
DOI:10.1038/s41467-018-04133-8