Copper(I) π-complexes with allyl derivatives of heterocyclic compounds: structural survey of their crystal engineering

In this review an exhaustive crystallochemical analysis of copper(I) π-complexes with allyl derivatives of heterocyclic compounds has been performed. Structural genesis of inorganic constituents starting from the simplest units to the most complicated aggregates was considered taking into account th...

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Bibliographic Details
Published in:Central European journal of chemistry 2013-12, Vol.11 (12), p.1875-1901
Main Authors: Slyvka, Yurii, Goreshnik, Evgeny, Pavlyuk, Oleksii, Mys’kiv, Marian
Format: Article
Language:English
Subjects:
Biochemistry
Biological and Medical Physics
Biophysics
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copper(I)
Crystal Engineering
Geochemistry
Heterocyclic Allyl Derivatives
Review Article
Structure
π-Complex
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Summary:In this review an exhaustive crystallochemical analysis of copper(I) π-complexes with allyl derivatives of heterocyclic compounds has been performed. Structural genesis of inorganic constituents starting from the simplest units to the most complicated aggregates was considered taking into account the specific role of Cu-(C=C) interaction, the construction of the organic ligands, the basicity and nucleophilic activity of their heteroatoms, as well as olefin Cu(I) π-complex preparation route.
ISSN:1895-1066
2391-5420
1644-3624
2391-5420
DOI:10.2478/s11532-013-0323-3