Dichlorido(4,4′-di- tert -butyl-2,2′-bipyridine-κ 2 N , N ′)palladium(II) dimethyl sulfoxide monosolvate monohydrate

The title compound, [PdCl 2 (C 18 H 24 N 2 )]·(CH 3 ) 2 SO·H 2 O, the Pd II ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide a...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-06, Vol.70 (6), p.m200-m201
Main Authors: Gutiérrez-Márquez, Ricardo A., Crisóstomo-Lucas, Carmela, Reyes-Martínez, Reyna, Hernández-Ortega, Simón, Morales-Morales, David
Format: Article
Language:English
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Summary:The title compound, [PdCl 2 (C 18 H 24 N 2 )]·(CH 3 ) 2 SO·H 2 O, the Pd II ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water molecules form linear chains along [100] by O—H...O and O—H...S hydrogen bonds, generating eight- and 12-membered rings. C—H...Cl interactions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di- tert -butyl-2,2′-bipyridine ligand exhibits π–π stacking interactions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536814009453