Iodine-Catalyzed Synthesis of 3‑Arylthioindoles Employing a 1‑Aryltriazene/CS2 Combination as a New Sulfenylation Source

A practical approach for the regioselective synthesis of 3-arylthioindoles has been accomplished using a combination of 1-aryltriazene/CS2 as a new sulfenylation source. The methodology employs molecular iodine as a catalyst and is compatible with a variety of structurally diverse reactants.

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Published in:ACS omega 2020-04, Vol.5 (13), p.7627-7635
Main Authors: Pandey, Anand Kumar, Chand, Shiv, Singh, Rahul, Kumar, Saurabh, Singh, Krishna Nand
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creator Pandey, Anand Kumar
Chand, Shiv
Singh, Rahul
Kumar, Saurabh
Singh, Krishna Nand
description A practical approach for the regioselective synthesis of 3-arylthioindoles has been accomplished using a combination of 1-aryltriazene/CS2 as a new sulfenylation source. The methodology employs molecular iodine as a catalyst and is compatible with a variety of structurally diverse reactants.
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title Iodine-Catalyzed Synthesis of 3‑Arylthioindoles Employing a 1‑Aryltriazene/CS2 Combination as a New Sulfenylation Source
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