Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4',5'-e]pyr...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 1999-03, Vol.4 (3), p.69-72
Main Authors: Guan, Xiao-Pei, Yan, Hong, Sun, Jian-Guang, Yu, Yong-Zhong
Format: Article
Language:English
Subjects:
Carbon
Chemical bonds
hexabenzylhexaazaisowurtzitane
iminium cation
Nitrates
Oxidation
Oxidative cleavage
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Summary:Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4',5'-e]pyrazine dinitrate (2).
ISSN:1420-3049
1420-3049
DOI:10.3390/40300069