Synthesis and Characterization of Novel Thiosalicylate-based Solid-Supported Ionic Liquid for Removal of Pb(II) Ions from Aqueous Solution

• Published in: Molecules (Basel, Switzerland) Switzerland), 2023-01, Vol.28 (2), p.830
• Main Authors: Kamaruddin, Nur Anis Liyana, Taha, Mohd Faisal, Wilfred, Cecilia Devi
• Format: Article
• Language: English
• Subjects: Adsorption; Aqueous solutions; Chemical precipitation; Chemicals; Correlation coefficient; Correlation coefficients; Covalent bonds; Ionic liquids; Ionic Liquids - chemistry; Ions; Ions - chemistry; Isotherms; Kinetics; Lead; Metals; NMR; Nuclear magnetic resonance; Pb(II) removal; Petroleum industry; Pollutants; Room temperature; Silica; Silica gel; Silica Gel - chemistry; solid-supported ionic liquids; Solvents; Structural analysis; thiosalicylate; Titration; Water; Water Pollutants, Chemical - chemistry; Water treatment
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules28020830

The main objectives of this study are to synthesize a new solid-supported ionic liquid (SSIL) that has a covalent bond between the solid support, i.e., activated silica gel, with thiosalicylate-based ionic liquid and to evaluate the performance of this new SSIL as an extractant, labelled as Si-TS-SSIL, and to remove Pb(II) ions from an aqueous solution. In this study, 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium thiosalicylate ([MTMSPI][TS]) ionic liquid was synthesized and the formation of [MTMSPI][TS] was confirmed through structural analysis using NMR, FTIR, IC, TGA, and Karl Fischer Titration. The [MTMSPI][TS] ionic liquid was then chemically immobilized on activated silica gel to produce a new thiosalicylate-based solid-supported ionic liquid (Si-TS-SSIL). The formation of these covalent bonds on Si-TS-SSIL was confirmed by solid-state NMR analysis. Meanwhile, BET analysis was performed to study the surface area of the activated silica gel and the prepared Si-TS-SSIL (before and after washing with solvent) with the purpose to show that all physically immobilized [MTMSPI][TS] has been washed off from Si-TS-SSIL, leaving only chemically immobilized [MTMSPI][TS] on Si-TS-SSIL before proceeding with removal study. The removal study of Pb(II) ions from an aqueous solution was carried out using Si-TS-SSIL as an extractant, whereby the amount of Pb(II) ions removed was determined by AAS. In this removal study, the experiments were carried out at a fixed agitation speed (400 rpm) and fixed amount of Si-TS-SSIL (0.25 g), with different contact times ranging from 2 to 250 min at room temperature. The maximum removal capacity was found to be 8.37 mg/g. The kinetics study was well fitted with the pseudo-second order model. Meanwhile, for the isotherm study, the removal process of Pb(II) ions was well described by the Freundlich isotherm model, as this model exhibited a higher correlation coefficient (R ), i.e., 0.99, as compared to the Langmuir isotherm model.