Evaluation of Natural Antioxidants Action in Oxidative Stability of Commercial Biodiesel

The use of biodiesel has grown year-by-year, mainly due the low emission of pollutant gases. In addition, the raw materials used in its production are renewable, different from petroleum fuel. However, the biodiesels are more susceptible to oxidative degradation during the storage period, what damag...

Full description

Saved in:
Bibliographic Details
Published in:Orbital : The Electronic Journal of Chemistry 2018-01, Vol.10 (1), p.26-30
Main Authors: Talita Cuenca Pina Moreira Ramos, Eliane Ferreira de Souza, Camila Cuenca Pina, Alberto Adriano Cavalheiro, Antonio Rogério Fiorucci, Margarete Soares da Silva
Format: Article
Language:English
Subjects:
eugenol
grape seed oil
induction period
rancimat
vitamin e
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 30
container_issue 1
container_start_page 26
container_title Orbital : The Electronic Journal of Chemistry
container_volume 10
creator Talita Cuenca Pina Moreira Ramos
Eliane Ferreira de Souza
Camila Cuenca Pina
Alberto Adriano Cavalheiro
Antonio Rogério Fiorucci
Margarete Soares da Silva
description The use of biodiesel has grown year-by-year, mainly due the low emission of pollutant gases. In addition, the raw materials used in its production are renewable, different from petroleum fuel. However, the biodiesels are more susceptible to oxidative degradation during the storage period, what damages the product quality. According the actual legislation, the use of antioxidant additives is necessary in order to provide a good resistance against oxidative reactions, which can be determined through accelerated oxidation tests, known as Rancimat method. The synthetic antioxidants tert-butylhydroquinone and butylated hydroxytoluene are among the most used, but several natural antioxidants could also be used. Thus, this work aims to evaluate the antioxidant properties of some natural antioxidants by using the Rancimat method. Two commercial biodiesel samples were added of three types of antioxidant at different levels of concentrations and submitted to accelerated oxidation in order to determine the induction periods. Different from vitamin E and grape seed oil, the eugenol additive presented the highest induction periods, being the most promising antioxidant additive for using in commercial biodiesel.   DOI: http://dx.doi.org/10.17807/orbital.v10i1.1027
doi_str_mv 10.17807/orbital.v10i1.1027
format article
fullrecord <record><control><sourceid>doaj</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_dbc10048ca734b2c82a28bd825884532</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_dbc10048ca734b2c82a28bd825884532</doaj_id><sourcerecordid>oai_doaj_org_article_dbc10048ca734b2c82a28bd825884532</sourcerecordid><originalsourceid>FETCH-doaj_primary_oai_doaj_org_article_dbc10048ca734b2c82a28bd8258845323</originalsourceid><addsrcrecordid>eNqtjM1KAzEUhYMgtGifwE1eoGOSSZvMspaKbuxCF-7CzU_llsxEknSwb--0-AiezYHv8B1CHjhruNJMPaZssUJsRs6QN5wJdUPmvNNyuZZCz8iilCOb0nZK6W5OPncjxBNUTANNB_oG9ZQh0s0wkR_0MNRCN-4640D3F1RxDPS9gsWI9XyxtqnvQ3Y4iU-YPIYS4j25PUAsYfHXd-T1efexfVn6BEfznbGHfDYJ0FxByl8GckUXg_HWccakdqBaaYXTAoS2XouV1nLVivY_v34BrsBi6w</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Evaluation of Natural Antioxidants Action in Oxidative Stability of Commercial Biodiesel</title><source>EZB Electronic Journals Library</source><creator>Talita Cuenca Pina Moreira Ramos ; Eliane Ferreira de Souza ; Camila Cuenca Pina ; Alberto Adriano Cavalheiro ; Antonio Rogério Fiorucci ; Margarete Soares da Silva</creator><creatorcontrib>Talita Cuenca Pina Moreira Ramos ; Eliane Ferreira de Souza ; Camila Cuenca Pina ; Alberto Adriano Cavalheiro ; Antonio Rogério Fiorucci ; Margarete Soares da Silva</creatorcontrib><description>The use of biodiesel has grown year-by-year, mainly due the low emission of pollutant gases. In addition, the raw materials used in its production are renewable, different from petroleum fuel. However, the biodiesels are more susceptible to oxidative degradation during the storage period, what damages the product quality. According the actual legislation, the use of antioxidant additives is necessary in order to provide a good resistance against oxidative reactions, which can be determined through accelerated oxidation tests, known as Rancimat method. The synthetic antioxidants tert-butylhydroquinone and butylated hydroxytoluene are among the most used, but several natural antioxidants could also be used. Thus, this work aims to evaluate the antioxidant properties of some natural antioxidants by using the Rancimat method. Two commercial biodiesel samples were added of three types of antioxidant at different levels of concentrations and submitted to accelerated oxidation in order to determine the induction periods. Different from vitamin E and grape seed oil, the eugenol additive presented the highest induction periods, being the most promising antioxidant additive for using in commercial biodiesel.   DOI: http://dx.doi.org/10.17807/orbital.v10i1.1027</description><identifier>EISSN: 1984-6428</identifier><identifier>DOI: 10.17807/orbital.v10i1.1027</identifier><language>eng</language><publisher>Universidade Federal de Mato Grosso do Sul</publisher><subject>eugenol ; grape seed oil ; induction period ; rancimat ; vitamin e</subject><ispartof>Orbital : The Electronic Journal of Chemistry, 2018-01, Vol.10 (1), p.26-30</ispartof><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Talita Cuenca Pina Moreira Ramos</creatorcontrib><creatorcontrib>Eliane Ferreira de Souza</creatorcontrib><creatorcontrib>Camila Cuenca Pina</creatorcontrib><creatorcontrib>Alberto Adriano Cavalheiro</creatorcontrib><creatorcontrib>Antonio Rogério Fiorucci</creatorcontrib><creatorcontrib>Margarete Soares da Silva</creatorcontrib><title>Evaluation of Natural Antioxidants Action in Oxidative Stability of Commercial Biodiesel</title><title>Orbital : The Electronic Journal of Chemistry</title><description>The use of biodiesel has grown year-by-year, mainly due the low emission of pollutant gases. In addition, the raw materials used in its production are renewable, different from petroleum fuel. However, the biodiesels are more susceptible to oxidative degradation during the storage period, what damages the product quality. According the actual legislation, the use of antioxidant additives is necessary in order to provide a good resistance against oxidative reactions, which can be determined through accelerated oxidation tests, known as Rancimat method. The synthetic antioxidants tert-butylhydroquinone and butylated hydroxytoluene are among the most used, but several natural antioxidants could also be used. Thus, this work aims to evaluate the antioxidant properties of some natural antioxidants by using the Rancimat method. Two commercial biodiesel samples were added of three types of antioxidant at different levels of concentrations and submitted to accelerated oxidation in order to determine the induction periods. Different from vitamin E and grape seed oil, the eugenol additive presented the highest induction periods, being the most promising antioxidant additive for using in commercial biodiesel.   DOI: http://dx.doi.org/10.17807/orbital.v10i1.1027</description><subject>eugenol</subject><subject>grape seed oil</subject><subject>induction period</subject><subject>rancimat</subject><subject>vitamin e</subject><issn>1984-6428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNqtjM1KAzEUhYMgtGifwE1eoGOSSZvMspaKbuxCF-7CzU_llsxEknSwb--0-AiezYHv8B1CHjhruNJMPaZssUJsRs6QN5wJdUPmvNNyuZZCz8iilCOb0nZK6W5OPncjxBNUTANNB_oG9ZQh0s0wkR_0MNRCN-4640D3F1RxDPS9gsWI9XyxtqnvQ3Y4iU-YPIYS4j25PUAsYfHXd-T1efexfVn6BEfznbGHfDYJ0FxByl8GckUXg_HWccakdqBaaYXTAoS2XouV1nLVivY_v34BrsBi6w</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Talita Cuenca Pina Moreira Ramos</creator><creator>Eliane Ferreira de Souza</creator><creator>Camila Cuenca Pina</creator><creator>Alberto Adriano Cavalheiro</creator><creator>Antonio Rogério Fiorucci</creator><creator>Margarete Soares da Silva</creator><general>Universidade Federal de Mato Grosso do Sul</general><scope>DOA</scope></search><sort><creationdate>20180101</creationdate><title>Evaluation of Natural Antioxidants Action in Oxidative Stability of Commercial Biodiesel</title><author>Talita Cuenca Pina Moreira Ramos ; Eliane Ferreira de Souza ; Camila Cuenca Pina ; Alberto Adriano Cavalheiro ; Antonio Rogério Fiorucci ; Margarete Soares da Silva</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-doaj_primary_oai_doaj_org_article_dbc10048ca734b2c82a28bd8258845323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>eugenol</topic><topic>grape seed oil</topic><topic>induction period</topic><topic>rancimat</topic><topic>vitamin e</topic><toplevel>online_resources</toplevel><creatorcontrib>Talita Cuenca Pina Moreira Ramos</creatorcontrib><creatorcontrib>Eliane Ferreira de Souza</creatorcontrib><creatorcontrib>Camila Cuenca Pina</creatorcontrib><creatorcontrib>Alberto Adriano Cavalheiro</creatorcontrib><creatorcontrib>Antonio Rogério Fiorucci</creatorcontrib><creatorcontrib>Margarete Soares da Silva</creatorcontrib><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Orbital : The Electronic Journal of Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Talita Cuenca Pina Moreira Ramos</au><au>Eliane Ferreira de Souza</au><au>Camila Cuenca Pina</au><au>Alberto Adriano Cavalheiro</au><au>Antonio Rogério Fiorucci</au><au>Margarete Soares da Silva</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evaluation of Natural Antioxidants Action in Oxidative Stability of Commercial Biodiesel</atitle><jtitle>Orbital : The Electronic Journal of Chemistry</jtitle><date>2018-01-01</date><risdate>2018</risdate><volume>10</volume><issue>1</issue><spage>26</spage><epage>30</epage><pages>26-30</pages><eissn>1984-6428</eissn><abstract>The use of biodiesel has grown year-by-year, mainly due the low emission of pollutant gases. In addition, the raw materials used in its production are renewable, different from petroleum fuel. However, the biodiesels are more susceptible to oxidative degradation during the storage period, what damages the product quality. According the actual legislation, the use of antioxidant additives is necessary in order to provide a good resistance against oxidative reactions, which can be determined through accelerated oxidation tests, known as Rancimat method. The synthetic antioxidants tert-butylhydroquinone and butylated hydroxytoluene are among the most used, but several natural antioxidants could also be used. Thus, this work aims to evaluate the antioxidant properties of some natural antioxidants by using the Rancimat method. Two commercial biodiesel samples were added of three types of antioxidant at different levels of concentrations and submitted to accelerated oxidation in order to determine the induction periods. Different from vitamin E and grape seed oil, the eugenol additive presented the highest induction periods, being the most promising antioxidant additive for using in commercial biodiesel.   DOI: http://dx.doi.org/10.17807/orbital.v10i1.1027</abstract><pub>Universidade Federal de Mato Grosso do Sul</pub><doi>10.17807/orbital.v10i1.1027</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier EISSN: 1984-6428
ispartof Orbital : The Electronic Journal of Chemistry, 2018-01, Vol.10 (1), p.26-30
issn 1984-6428
language eng
recordid cdi_doaj_primary_oai_doaj_org_article_dbc10048ca734b2c82a28bd825884532
source EZB Electronic Journals Library
subjects eugenol
grape seed oil
induction period
rancimat
vitamin e
title Evaluation of Natural Antioxidants Action in Oxidative Stability of Commercial Biodiesel
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T08%3A57%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-doaj&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Evaluation%20of%20Natural%20Antioxidants%20Action%20in%20Oxidative%20Stability%20of%20Commercial%20Biodiesel&rft.jtitle=Orbital%20:%20The%20Electronic%20Journal%20of%20Chemistry&rft.au=Talita%20Cuenca%20Pina%20Moreira%20Ramos&rft.date=2018-01-01&rft.volume=10&rft.issue=1&rft.spage=26&rft.epage=30&rft.pages=26-30&rft.eissn=1984-6428&rft_id=info:doi/10.17807/orbital.v10i1.1027&rft_dat=%3Cdoaj%3Eoai_doaj_org_article_dbc10048ca734b2c82a28bd825884532%3C/doaj%3E%3Cgrp_id%3Ecdi_FETCH-doaj_primary_oai_doaj_org_article_dbc10048ca734b2c82a28bd8258845323%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true