Synthesis of 2,6-disubstituted tetrahydroazulene derivatives

Synthesis of hydroazulene derivatives has been carried out through a ring-enlargement route by using carbene adduct intermediates. The protocol can be applied for the construction of functionalized hydroazulene skeletons as key components of many natural products as well as the core system of novel...

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Bibliographic Details
Published in:Beilstein journal of organic chemistry 2012-05, Vol.8 (1), p.693-698
Main Authors: Hussain, Zakir, Hopf, Henning, Ayub, Khurshid, Eichhorn, S Holger
Format: Article
Language:English
Subjects:
carbene addition
Chemistry
Full Research Paper
hydroazulenes
liquid crystals
ring expansion
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Summary:Synthesis of hydroazulene derivatives has been carried out through a ring-enlargement route by using carbene adduct intermediates. The protocol can be applied for the construction of functionalized hydroazulene skeletons as key components of many natural products as well as the core system of novel liquid-crystalline materials.
ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.8.77