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Evaluation of the Degradation Process of Diethyl (3H-1-Ethoxy-3-phenoxazinylidene) Ammonium Chloride in Water, after Exposure to Nonthermal Plasma at Atmospheric Pressure

The present study characterizes the degradation of diethyl dye (3H-1-ethoxy-3-phenoxazinylidene) ammonium chloride in water (concentration of 20.00 mg/L), after its exposure to nonthermal plasma of air at atmospheric pressure. The exposure time of the solution of interest to the plasma was 250 minut...

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Published in:Journal of chemistry 2022-06, Vol.2022, p.1-8
Main Authors: Alarcón Hernández, Fidel Benjamín, Fuentes Albarrán, María del Carmen, Gadea Pacheco, José Luis, Tlatelpa Becerro, Ángel, Cañete Cabrera, Víctor Aristeo
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Fuentes Albarrán, María del Carmen
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Cañete Cabrera, Víctor Aristeo
description The present study characterizes the degradation of diethyl dye (3H-1-ethoxy-3-phenoxazinylidene) ammonium chloride in water (concentration of 20.00 mg/L), after its exposure to nonthermal plasma of air at atmospheric pressure. The exposure time of the solution of interest to the plasma was 250 minutes per treatment. Four different nonthermal plasma generation conditions were considered (15, 20, 25, and 30 mA) at a voltage of 2000 V. The change in dilution was determined by UV/VIS spectrophotometry (absorbance and concentration), chemical oxygen demand (COD), pH, and bioassays with lettuce seeds (Lactuca sativa). Given the increase in temperature of the sample under study due to exposure to plasma, the change in each of the measured parameters was also explored as an exclusive function of the increase in temperature (27°C to 44°C). The measurements did not show the influence of temperature on the changes observed in the parameters of interest in this experiment. In general, the maximum degradation obtained from the samples analyzed at the end of the treatments corresponds to the 30 mA treatment. For this, reductions of 70.4% in absorbance, 71.5% of dye concentration, 81.6% of COD, and 51.85% of pH were achieved. The germination percentage of the lettuce seeds obtained was 74%. The degradation of the dye in the solution of interest depends on the plasma generating parameters high power and the high degradation rate.
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For this, reductions of 70.4% in absorbance, 71.5% of dye concentration, 81.6% of COD, and 51.85% of pH were achieved. The germination percentage of the lettuce seeds obtained was 74%. The degradation of the dye in the solution of interest depends on the plasma generating parameters high power and the high degradation rate.</description><identifier>ISSN: 2090-9063</identifier><identifier>EISSN: 2090-9071</identifier><identifier>DOI: 10.1155/2022/4486227</identifier><language>eng</language><publisher>New York: Hindawi</publisher><subject>Absorbance ; Ammonium chloride ; Ammonium compounds ; Ammonium paratungstate ; Analysis ; Atmospheric pressure ; Bioassays ; By products ; Calibration ; Chemical oxygen demand ; Chloride ; Chlorides ; Chlorofluorocarbons ; Degradation ; Dilution ; Dyes ; Effluents ; Electric currents ; Electrodes ; Experiments ; Exposure ; Gases ; Germination ; Parameters ; Plasma ; Plasma physics ; Seeds ; Spectrophotometry ; Textile industry ; VOCs ; Volatile organic compounds ; Water pollution</subject><ispartof>Journal of chemistry, 2022-06, Vol.2022, p.1-8</ispartof><rights>Copyright © 2022 Fidel Benjamín Alarcón Hernández et al.</rights><rights>COPYRIGHT 2022 John Wiley &amp; Sons, Inc.</rights><rights>Copyright © 2022 Fidel Benjamín Alarcón Hernández et al. 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subjects Absorbance
Ammonium chloride
Ammonium compounds
Ammonium paratungstate
Analysis
Atmospheric pressure
Bioassays
By products
Calibration
Chemical oxygen demand
Chloride
Chlorides
Chlorofluorocarbons
Degradation
Dilution
Dyes
Effluents
Electric currents
Electrodes
Experiments
Exposure
Gases
Germination
Parameters
Plasma
Plasma physics
Seeds
Spectrophotometry
Textile industry
VOCs
Volatile organic compounds
Water pollution
title Evaluation of the Degradation Process of Diethyl (3H-1-Ethoxy-3-phenoxazinylidene) Ammonium Chloride in Water, after Exposure to Nonthermal Plasma at Atmospheric Pressure
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