Potassium N -bromo-4-chloro-2-methylbenzenesulfonamidate monohydrate

In the title compound, K+·C7H6BrClNO2S−·H2O, the K+ cation is heptacoordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methylbenzenesulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584 (3) Å is consistent with an S=N double bo...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-07, Vol.69 (7), p.m370-m370
Main Authors: Spandana, H. S., Foro, Sabine, Gowda, B. Thimme
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In the title compound, K+·C7H6BrClNO2S−·H2O, the K+ cation is heptacoordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methylbenzenesulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584 (3) Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O-H...Br and O-H...N hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813014979