Bromidotris(triphenyl-phosphane)silver acetonitrile monosolvate monohydrate

In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetra-hedral, with the three Ag-P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag-Br bond slightly longer [2.7242 (5) Å]. The coordination tetra-hedron...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-11, Vol.67 (Pt 11), p.m1507-m1507
Main Authors: Owczarzak, Anita M, Kyros, Loukas, Hadjikakou, Sotiris K, Kubicki, Maciej
Format: Article
Language:English
Subjects:
Metal-Organic Papers
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In the title compound, [AgBr(C(18)H(15)P)(3)]·C(2)H(3)N·H(2)O, the coordination of the Ag atom is close to ideal tetra-hedral, with the three Ag-P bond lengths almost equal [2.5441 (10), 2.5523 (9) and 2.5647 (10) ° A] and the Ag-Br bond slightly longer [2.7242 (5) Å]. The coordination tetra-hedron is slightly flattened, the Ag atom is closer to the PPP plane; the P-Ag-P angles are wider than the Br-Ag-P angles. The voids in the crystal structure are filled with ordered acetonitrile solvent mol-ecules. The remaining electron density was inter-preted as a water mol-ecule, disordered over three alternative positions. Neither of the solvent mol-ecules is connected by any directional specific inter-actions with the complex.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811040827