Bimetallic Pt-Ni Nanoparticles Confined in Porous Titanium Oxide Cage for Hydrogen Generation from NaBH4 Hydrolysis

Sodium borohydride (NaBH4), with a high theoretical hydrogen content (10.8 wt%) and safe characteristics, has been widely employed to produce hydrogen based on hydrolysis reactions. In this work, a porous titanium oxide cage (PTOC) has been synthesized by a one-step hydrothermal method using NH2-MIL...

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Published in:Nanomaterials (Basel, Switzerland) Switzerland), 2022-07, Vol.12 (15), p.2550
Main Authors: Yu, Yuqian, Kang, Li, Sun, Lixian, Xu, Fen, Pan, Hongge, Sang, Zhen, Zhang, Chenchen, Jia, Xinlei, Sui, Qingli, Bu, Yiting, Cai, Dan, Xia, Yongpeng, Zhang, Kexiang, Li, Bin
Format: Article
Language:English
Subjects:
Alanine
Bimetals
Borohydrides
Cages
Carbon
Catalysis
Catalysts
Catalytic activity
Energy
Ethanol
Hydrogen
hydrogen generation
Hydrogen production
Hydrolysis
Intermetallic compounds
L-Alanine
Morphology
Nanoparticles
Nitrates
Porous materials
porous titanium oxide cage
PtNi nanoparticles
sodium borohydride hydrolysis
Spectrum analysis
Synergistic effect
Titanium
Titanium oxide
Titanium oxides
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creator Yu, Yuqian
Kang, Li
Sun, Lixian
Xu, Fen
Pan, Hongge
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Jia, Xinlei
Sui, Qingli
Bu, Yiting
Cai, Dan
Xia, Yongpeng
Zhang, Kexiang
Li, Bin
description Sodium borohydride (NaBH4), with a high theoretical hydrogen content (10.8 wt%) and safe characteristics, has been widely employed to produce hydrogen based on hydrolysis reactions. In this work, a porous titanium oxide cage (PTOC) has been synthesized by a one-step hydrothermal method using NH2-MIL-125 as the template and L-alanine as the coordination agent. Due to the evenly distributed PtNi alloy particles with more catalytically active sites, and the synergistic effect between the PTOC and PtNi alloy particles, the PtNi/PTOC catalyst presents a high hydrogen generation rate (10,164.3 mL∙min−1∙g−1) and low activation energy (28.7 kJ∙mol−1). Furthermore, the robust porous structure of PTOC effectively suppresses the agglomeration issue; thus, the PtNi/PTOC catalyst retains 87.8% of the initial catalytic activity after eight cycles. These results indicate that the PtNi/PTOC catalyst has broad applications for the hydrolysis of borohydride.
doi_str_mv 10.3390/nano12152550
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subjects Alanine
Bimetals
Borohydrides
Cages
Carbon
Catalysis
Catalysts
Catalytic activity
Energy
Ethanol
Hydrogen
hydrogen generation
Hydrogen production
Hydrolysis
Intermetallic compounds
L-Alanine
Morphology
Nanoparticles
Nitrates
Porous materials
porous titanium oxide cage
PtNi nanoparticles
sodium borohydride hydrolysis
Spectrum analysis
Synergistic effect
Titanium
Titanium oxide
Titanium oxides
title Bimetallic Pt-Ni Nanoparticles Confined in Porous Titanium Oxide Cage for Hydrogen Generation from NaBH4 Hydrolysis
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