Dibromido(dimethyl sulfoxide-κ O )(6-methyl-2,2′-bipyridine-κ 2 N , N ′)cadmium

In the title compound, [CdBr 2 (C 11 H 10 N 2 )(C 2 H 6 OS)], the Cd II atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intramolecular C—H...O hydrogen bond o...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-08, Vol.68 (8), p.m1124-m1124
Main Authors: Shirvan, Sadif A., Haydari Dezfuli, Sara
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:In the title compound, [CdBr 2 (C 11 H 10 N 2 )(C 2 H 6 OS)], the Cd II atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intramolecular C—H...O hydrogen bond occurs. The crystal structure is stabilized by C—H...Br hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.582 (5) and 3.582 (5) Å].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812033168