Alkylation of ambident indole anion in ionic liquids

Alkylation of indole salts in different ionic liquids is reported. Ionic liquids increase the alkylation reaction rate of ambident indole anion and reduce the effects of counter ions and/or additives, the alkylation reaction rates being independent of the presence of small amounts of protic solvents...

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Bibliographic Details
Published in:Open Chemistry 2007-03, Vol.5 (1), p.156-168
Main Authors: Zicmanis, Andris, Vavilina, Galina, Drozdova, Svetlana, Mekss, Peteris, Klavins, Maris
Format: Article
Language:English
Subjects:
alkylation reactions
ambident anion
indole
Ionic liquids
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Summary:Alkylation of indole salts in different ionic liquids is reported. Ionic liquids increase the alkylation reaction rate of ambident indole anion and reduce the effects of counter ions and/or additives, the alkylation reaction rates being independent of the presence of small amounts of protic solvents or water.
ISSN:2391-5420
2391-5420
DOI:10.2478/s11532-006-0063-8