The Antisolvent Precipitation of CuZnOx Mixed Oxide Materials Using a Choline Chloride-Urea Deep Eutectic Solvent

Metal oxides have applications in a variety of different fields, and new synthesis methods are needed to control their properties and improve their performance as functional materials. In this study, we investigated a low-cost antisolvent precipitation method using a choline chloride-urea deep eutec...

Full description

Saved in:
Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2024-07, Vol.29 (14), p.3357
Main Authors: Wallace, William T, Hayward, James S, Marsh, Amy R, Bartley, Jonathan K
Format: Article
Language:English
Subjects:
Aqueous solutions
Carbon dioxide
Chloride
choline chloride
Copper
copper zinc oxide
deep eutectic solvent
Hydrogen bonds
Investigations
Metal oxides
Nitrates
Ratios
Solvents
Temperature
Water
Zinc oxides
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c320t-3453c497d05676990de015c2e0635a0200bc1af86e4c104f545d7be5ca73b2c43
container_end_page
container_issue 14
container_start_page 3357
container_title Molecules (Basel, Switzerland)
container_volume 29
creator Wallace, William T
Hayward, James S
Marsh, Amy R
Bartley, Jonathan K
description Metal oxides have applications in a variety of different fields, and new synthesis methods are needed to control their properties and improve their performance as functional materials. In this study, we investigated a low-cost antisolvent precipitation method using a choline chloride-urea deep eutectic solvent to precipitate CuZnOx materials using water as the antisolvent. Using this methodology, the metal oxide materials can be precipitated directly from the deep eutectic solvent without the need for a high-temperature calcination step that can lead to a reduction in defects and surface area, which are important properties in applications such as catalysis.
doi_str_mv 10.3390/molecules29143357
format article
fullrecord <record><control><sourceid>proquest_doaj_</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_e5c9ffd039fa46a790863f77268795f2</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_e5c9ffd039fa46a790863f77268795f2</doaj_id><sourcerecordid>3084981152</sourcerecordid><originalsourceid>FETCH-LOGICAL-c320t-3453c497d05676990de015c2e0635a0200bc1af86e4c104f545d7be5ca73b2c43</originalsourceid><addsrcrecordid>eNplkc1uEzEURi0EoqXwAGyQJTZsBq7_xuNlFQpUahUkmg0by_Fct44m49SeQeHtcUipEKyuZZ3z-VofIa8ZvBfCwIdtGtDPAxZumBRC6SfklEkOjQBpnv51PiEvStkAcCaZek5OqtxKI9Qpub-5Q3o-TrGk4QeOE_2a0cddnNwU00hToIv5-7jc0-u4x54u97FHeu0mzNENha5KHG-po4u7NMQR6xxSrkizyujoR8QdvZgn9FP09NvxhZfkWagqvnqYZ2T16eJm8aW5Wn6-XJxfNV5wmBohlfDS6B5Uq1tjoEdgynOEVigHHGDtmQtdi9IzkEFJ1es1Ku-0WHMvxRm5POb2yW3sLsetyz9tctH-vkj51rpc9xrQVsuE0IMwwcnWaQNdK4LWvO20UYHXrHfHrF1O9zOWyW5j8TgMbsQ0FyugU4wZY7qKvv0H3aQ5j_WnB0qajjF1CGRHyudUSsbwuCADe-jW_tdtdd48JM_rLfaPxp8yxS9OWqAr</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3084981152</pqid></control><display><type>article</type><title>The Antisolvent Precipitation of CuZnOx Mixed Oxide Materials Using a Choline Chloride-Urea Deep Eutectic Solvent</title><source>Publicly Available Content Database</source><source>PubMed Central</source><creator>Wallace, William T ; Hayward, James S ; Marsh, Amy R ; Bartley, Jonathan K</creator><creatorcontrib>Wallace, William T ; Hayward, James S ; Marsh, Amy R ; Bartley, Jonathan K</creatorcontrib><description>Metal oxides have applications in a variety of different fields, and new synthesis methods are needed to control their properties and improve their performance as functional materials. In this study, we investigated a low-cost antisolvent precipitation method using a choline chloride-urea deep eutectic solvent to precipitate CuZnOx materials using water as the antisolvent. Using this methodology, the metal oxide materials can be precipitated directly from the deep eutectic solvent without the need for a high-temperature calcination step that can lead to a reduction in defects and surface area, which are important properties in applications such as catalysis.</description><identifier>ISSN: 1420-3049</identifier><identifier>EISSN: 1420-3049</identifier><identifier>DOI: 10.3390/molecules29143357</identifier><identifier>PMID: 39064935</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Aqueous solutions ; Carbon dioxide ; Chloride ; choline chloride ; Copper ; copper zinc oxide ; deep eutectic solvent ; Hydrogen bonds ; Investigations ; Metal oxides ; Nitrates ; Ratios ; Solvents ; Temperature ; Water ; Zinc oxides</subject><ispartof>Molecules (Basel, Switzerland), 2024-07, Vol.29 (14), p.3357</ispartof><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c320t-3453c497d05676990de015c2e0635a0200bc1af86e4c104f545d7be5ca73b2c43</cites><orcidid>0000-0001-8468-3301 ; 0000-0002-1400-2520 ; 0000-0003-4640-541X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/3084981152/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/3084981152?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,25731,27901,27902,36989,36990,44566,74869</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39064935$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wallace, William T</creatorcontrib><creatorcontrib>Hayward, James S</creatorcontrib><creatorcontrib>Marsh, Amy R</creatorcontrib><creatorcontrib>Bartley, Jonathan K</creatorcontrib><title>The Antisolvent Precipitation of CuZnOx Mixed Oxide Materials Using a Choline Chloride-Urea Deep Eutectic Solvent</title><title>Molecules (Basel, Switzerland)</title><addtitle>Molecules</addtitle><description>Metal oxides have applications in a variety of different fields, and new synthesis methods are needed to control their properties and improve their performance as functional materials. In this study, we investigated a low-cost antisolvent precipitation method using a choline chloride-urea deep eutectic solvent to precipitate CuZnOx materials using water as the antisolvent. Using this methodology, the metal oxide materials can be precipitated directly from the deep eutectic solvent without the need for a high-temperature calcination step that can lead to a reduction in defects and surface area, which are important properties in applications such as catalysis.</description><subject>Aqueous solutions</subject><subject>Carbon dioxide</subject><subject>Chloride</subject><subject>choline chloride</subject><subject>Copper</subject><subject>copper zinc oxide</subject><subject>deep eutectic solvent</subject><subject>Hydrogen bonds</subject><subject>Investigations</subject><subject>Metal oxides</subject><subject>Nitrates</subject><subject>Ratios</subject><subject>Solvents</subject><subject>Temperature</subject><subject>Water</subject><subject>Zinc oxides</subject><issn>1420-3049</issn><issn>1420-3049</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNplkc1uEzEURi0EoqXwAGyQJTZsBq7_xuNlFQpUahUkmg0by_Fct44m49SeQeHtcUipEKyuZZ3z-VofIa8ZvBfCwIdtGtDPAxZumBRC6SfklEkOjQBpnv51PiEvStkAcCaZek5OqtxKI9Qpub-5Q3o-TrGk4QeOE_2a0cddnNwU00hToIv5-7jc0-u4x54u97FHeu0mzNENha5KHG-po4u7NMQR6xxSrkizyujoR8QdvZgn9FP09NvxhZfkWagqvnqYZ2T16eJm8aW5Wn6-XJxfNV5wmBohlfDS6B5Uq1tjoEdgynOEVigHHGDtmQtdi9IzkEFJ1es1Ku-0WHMvxRm5POb2yW3sLsetyz9tctH-vkj51rpc9xrQVsuE0IMwwcnWaQNdK4LWvO20UYHXrHfHrF1O9zOWyW5j8TgMbsQ0FyugU4wZY7qKvv0H3aQ5j_WnB0qajjF1CGRHyudUSsbwuCADe-jW_tdtdd48JM_rLfaPxp8yxS9OWqAr</recordid><startdate>20240717</startdate><enddate>20240717</enddate><creator>Wallace, William T</creator><creator>Hayward, James S</creator><creator>Marsh, Amy R</creator><creator>Bartley, Jonathan K</creator><general>MDPI AG</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0001-8468-3301</orcidid><orcidid>https://orcid.org/0000-0002-1400-2520</orcidid><orcidid>https://orcid.org/0000-0003-4640-541X</orcidid></search><sort><creationdate>20240717</creationdate><title>The Antisolvent Precipitation of CuZnOx Mixed Oxide Materials Using a Choline Chloride-Urea Deep Eutectic Solvent</title><author>Wallace, William T ; Hayward, James S ; Marsh, Amy R ; Bartley, Jonathan K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-3453c497d05676990de015c2e0635a0200bc1af86e4c104f545d7be5ca73b2c43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aqueous solutions</topic><topic>Carbon dioxide</topic><topic>Chloride</topic><topic>choline chloride</topic><topic>Copper</topic><topic>copper zinc oxide</topic><topic>deep eutectic solvent</topic><topic>Hydrogen bonds</topic><topic>Investigations</topic><topic>Metal oxides</topic><topic>Nitrates</topic><topic>Ratios</topic><topic>Solvents</topic><topic>Temperature</topic><topic>Water</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wallace, William T</creatorcontrib><creatorcontrib>Hayward, James S</creatorcontrib><creatorcontrib>Marsh, Amy R</creatorcontrib><creatorcontrib>Bartley, Jonathan K</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health &amp; Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><collection>Health &amp; Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Molecules (Basel, Switzerland)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wallace, William T</au><au>Hayward, James S</au><au>Marsh, Amy R</au><au>Bartley, Jonathan K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Antisolvent Precipitation of CuZnOx Mixed Oxide Materials Using a Choline Chloride-Urea Deep Eutectic Solvent</atitle><jtitle>Molecules (Basel, Switzerland)</jtitle><addtitle>Molecules</addtitle><date>2024-07-17</date><risdate>2024</risdate><volume>29</volume><issue>14</issue><spage>3357</spage><pages>3357-</pages><issn>1420-3049</issn><eissn>1420-3049</eissn><abstract>Metal oxides have applications in a variety of different fields, and new synthesis methods are needed to control their properties and improve their performance as functional materials. In this study, we investigated a low-cost antisolvent precipitation method using a choline chloride-urea deep eutectic solvent to precipitate CuZnOx materials using water as the antisolvent. Using this methodology, the metal oxide materials can be precipitated directly from the deep eutectic solvent without the need for a high-temperature calcination step that can lead to a reduction in defects and surface area, which are important properties in applications such as catalysis.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>39064935</pmid><doi>10.3390/molecules29143357</doi><orcidid>https://orcid.org/0000-0001-8468-3301</orcidid><orcidid>https://orcid.org/0000-0002-1400-2520</orcidid><orcidid>https://orcid.org/0000-0003-4640-541X</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1420-3049
ispartof Molecules (Basel, Switzerland), 2024-07, Vol.29 (14), p.3357
issn 1420-3049
1420-3049
language eng
recordid cdi_doaj_primary_oai_doaj_org_article_e5c9ffd039fa46a790863f77268795f2
source Publicly Available Content Database; PubMed Central
subjects Aqueous solutions
Carbon dioxide
Chloride
choline chloride
Copper
copper zinc oxide
deep eutectic solvent
Hydrogen bonds
Investigations
Metal oxides
Nitrates
Ratios
Solvents
Temperature
Water
Zinc oxides
title The Antisolvent Precipitation of CuZnOx Mixed Oxide Materials Using a Choline Chloride-Urea Deep Eutectic Solvent
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T22%3A09%3A36IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_doaj_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20Antisolvent%20Precipitation%20of%20CuZnOx%20Mixed%20Oxide%20Materials%20Using%20a%20Choline%20Chloride-Urea%20Deep%20Eutectic%20Solvent&rft.jtitle=Molecules%20(Basel,%20Switzerland)&rft.au=Wallace,%20William%20T&rft.date=2024-07-17&rft.volume=29&rft.issue=14&rft.spage=3357&rft.pages=3357-&rft.issn=1420-3049&rft.eissn=1420-3049&rft_id=info:doi/10.3390/molecules29143357&rft_dat=%3Cproquest_doaj_%3E3084981152%3C/proquest_doaj_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c320t-3453c497d05676990de015c2e0635a0200bc1af86e4c104f545d7be5ca73b2c43%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=3084981152&rft_id=info:pmid/39064935&rfr_iscdi=true