Morphology, Mechanical, and Water Barrier Properties of Carboxymethyl Rice Starch Films: Sodium Hydroxide Effect

• Published in: Molecules (Basel, Switzerland) Switzerland), 2022-01, Vol.27 (2), p.331
• Main Authors: Rachtanapun, Pornchai, Thanakkasaranee, Sarinthip, Auras, Rafael A, Chaiwong, Nareekan, Jantanasakulwong, Kittisak, Jantrawut, Pensak, Phimolsiripol, Yuthana, Seesuriyachan, Phisit, Leksawasdi, Noppol, Chaiyaso, Thanongsak, Somman, Sarana Rose, Ruksiriwanich, Warintorn, Klunklin, Warinporn, Reungsang, Alissara, Ngo, Thi Minh Phuong
• Format: Article
• Language: English
• Subjects: Calorimetry; Caustic soda; Cellulose; Cold; Contact angle; Contact melting; Differential scanning calorimetry; Elongation; Fourier transforms; Glycerol; Infrared spectroscopy; Mechanical properties; Melt temperature; Moisture absorption; Morphology; NaOH; Oryza - chemistry; Permeability; Pharmaceutical industry; Polymers; Rice; Sodium; Sodium hydroxide; Sodium Hydroxide - chemistry; Solubility; Starch; Starch - analogs & derivatives; Starch - chemistry; Starch - metabolism; Steam; Temperature; Tensile Strength; Textiles; Thermal properties; Viscosity; Water vapor; water vapor permeability; X-ray diffraction
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules27020331

Carboxymethyl rice starch films were prepared from carboxymethyl rice starch (CMSr) treated with sodium hydroxide (NaOH) at 10-50% / . The objective of this research was to determine the effect of NaOH concentrations on morphology, mechanical properties, and water barrier properties of the CMSr films. The degree of substitution (DS) and morphology of native rice starch and CMSr powders were examined. Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and differential scanning calorimetry (DSC) were used to investigate the chemical structure, crystallinity, and thermal properties of the CMSr films. As the NaOH concentrations increased, the DS of CMSr powders increased, which affected the morphology of CMSr powders; a polyhedral shape of the native rice starch was deformed. In addition, the increase in NaOH concentrations of the synthesis of CMSr resulted in an increase in water solubility, elongation at break, and water vapor permeability (WVP) of CMSr films. On the other hand, the water contact angle, melting temperature, and the tensile strength of the CMSr films decreased with increasing NaOH concentrations. However, the tensile strength of the CMSr films was relatively low. Therefore, such a property needs to be improved and the application of the developed films should be investigated in the future work.