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Ionic liquid-loaded triazine-based magnetic nanoparticles for promoting multicomponent reaction
A novel hybrid magnetic ionic-liquid as a heterogeneous catalyst was synthesized by hybridization of imidazolium based-ionic liquid onto the nitrogen rich magnetic nanocomposite. The resulting catalyst (n-Fe 3 O 4 @SiO 2 -TA-SO 3 H IL) has two advantages besides recyclability: (i) high capacity of f...
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| Published in: | Scientific reports 2022-12, Vol.12 (1), p.22261-12, Article 22261 |
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| Main Authors: | , , , |
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| cited_by | cdi_FETCH-LOGICAL-c540t-c6b36cbf92a11f5dd410e70bdca8fc18acaa1727db30e12d49cadd7886e6870b3 |
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| cites | cdi_FETCH-LOGICAL-c540t-c6b36cbf92a11f5dd410e70bdca8fc18acaa1727db30e12d49cadd7886e6870b3 |
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| container_start_page | 22261 |
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| creator | Kafshdarzadeh, Kosar Malmir, Masoume Amiri, Zahra Heravi, Majid M. |
| description | A novel hybrid magnetic ionic-liquid as a heterogeneous catalyst was synthesized by hybridization of imidazolium based-ionic liquid onto the nitrogen rich magnetic nanocomposite. The resulting catalyst (n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL) has two advantages besides recyclability: (i) high capacity of functional-SO
3
H group with imidazolium-IL cation for promoting symmetric and asymmetric Hantzsch reaction and (ii) easy recovery. Caused by the polymeric and magnetic nature of the n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL, large quantities of acidic groups were bound to the n-Fe
3
O
4
@SiO
2
-TA surface, which reduced the catalyst mass applied to the catalytic reaction. Moreover, superior catalytic performance and outstanding recyclability of n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL in mild condition make this method a green pathway for manufacture of satisfactory chemicals. |
| doi_str_mv | 10.1038/s41598-022-26235-6 |
| format | article |
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3
O
4
@SiO
2
-TA-SO
3
H IL) has two advantages besides recyclability: (i) high capacity of functional-SO
3
H group with imidazolium-IL cation for promoting symmetric and asymmetric Hantzsch reaction and (ii) easy recovery. Caused by the polymeric and magnetic nature of the n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL, large quantities of acidic groups were bound to the n-Fe
3
O
4
@SiO
2
-TA surface, which reduced the catalyst mass applied to the catalytic reaction. Moreover, superior catalytic performance and outstanding recyclability of n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL in mild condition make this method a green pathway for manufacture of satisfactory chemicals.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-022-26235-6</identifier><identifier>PMID: 36564418</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/638/77 ; 639/638/77/884 ; 639/638/77/885 ; 639/638/77/887 ; Catalysts ; Chemistry ; Humanities and Social Sciences ; Hybridization ; Ions ; Iron oxides ; Morphology ; multidisciplinary ; Nanocomposites ; Nanoparticles ; Nitrogen ; Science ; Science (multidisciplinary) ; Silicon dioxide ; Sulfur ; Triazine</subject><ispartof>Scientific reports, 2022-12, Vol.12 (1), p.22261-12, Article 22261</ispartof><rights>The Author(s) 2022</rights><rights>2022. The Author(s).</rights><rights>The Author(s) 2022. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c540t-c6b36cbf92a11f5dd410e70bdca8fc18acaa1727db30e12d49cadd7886e6870b3</citedby><cites>FETCH-LOGICAL-c540t-c6b36cbf92a11f5dd410e70bdca8fc18acaa1727db30e12d49cadd7886e6870b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2757232428/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2757232428?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36564418$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kafshdarzadeh, Kosar</creatorcontrib><creatorcontrib>Malmir, Masoume</creatorcontrib><creatorcontrib>Amiri, Zahra</creatorcontrib><creatorcontrib>Heravi, Majid M.</creatorcontrib><title>Ionic liquid-loaded triazine-based magnetic nanoparticles for promoting multicomponent reaction</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>A novel hybrid magnetic ionic-liquid as a heterogeneous catalyst was synthesized by hybridization of imidazolium based-ionic liquid onto the nitrogen rich magnetic nanocomposite. The resulting catalyst (n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL) has two advantages besides recyclability: (i) high capacity of functional-SO
3
H group with imidazolium-IL cation for promoting symmetric and asymmetric Hantzsch reaction and (ii) easy recovery. Caused by the polymeric and magnetic nature of the n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL, large quantities of acidic groups were bound to the n-Fe
3
O
4
@SiO
2
-TA surface, which reduced the catalyst mass applied to the catalytic reaction. Moreover, superior catalytic performance and outstanding recyclability of n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL in mild condition make this method a green pathway for manufacture of satisfactory chemicals.</description><subject>639/638/77</subject><subject>639/638/77/884</subject><subject>639/638/77/885</subject><subject>639/638/77/887</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Humanities and Social Sciences</subject><subject>Hybridization</subject><subject>Ions</subject><subject>Iron oxides</subject><subject>Morphology</subject><subject>multidisciplinary</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Nitrogen</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Silicon dioxide</subject><subject>Sulfur</subject><subject>Triazine</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNp9kstu1TAQhi0EolXpC7BAkdiwMfgWx9kgoYrLkSqxgbU1sZ3go8RO7QSJPj1OcygtC7zxePz7mxnPIPSSkreUcPUuC1q3ChPGMJOM11g-QeeMiBozztjTB_YZusz5SMqqWSto-xydcVlLIag6R_oQgzfV6G9Wb_EYwTpbLcnDrQ8Od5DLcYIhuKWoAoQ4Qyrm6HLVx1TNKU5x8WGopnUs_jjNMbiwVMmBWXwML9CzHsbsLk_7Bfr-6eO3qy_4-uvnw9WHa2xqQRZsZMel6fqWAaV9ba2gxDWkswZUb6gCA0Ab1tiOE0eZFa0BaxulpJOq6PgFOuxcG-Go5-QnSL90BK_vHDEN-pS4dqCU4Q563hOhSKusIpJIzgkjRBhZWO931rx2k7Om1JNgfAR9fBP8Dz3En7ptVFuQBfDmBEjxZnV50ZPPxo0jBBfXrFlTK0qlqrdYr_-RHuOaQvmqTdWU_gm2AdmuMinmnFx_nwwlehsHvY-DLuOg78ZBb-hXD8u4f_Kn-UXAd0EuV2Fw6W_s_2B_AyMzwmM</recordid><startdate>20221223</startdate><enddate>20221223</enddate><creator>Kafshdarzadeh, Kosar</creator><creator>Malmir, Masoume</creator><creator>Amiri, Zahra</creator><creator>Heravi, Majid M.</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><general>Nature Portfolio</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope></search><sort><creationdate>20221223</creationdate><title>Ionic liquid-loaded triazine-based magnetic nanoparticles for promoting multicomponent reaction</title><author>Kafshdarzadeh, Kosar ; Malmir, Masoume ; Amiri, Zahra ; Heravi, Majid M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c540t-c6b36cbf92a11f5dd410e70bdca8fc18acaa1727db30e12d49cadd7886e6870b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>639/638/77</topic><topic>639/638/77/884</topic><topic>639/638/77/885</topic><topic>639/638/77/887</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Humanities and Social Sciences</topic><topic>Hybridization</topic><topic>Ions</topic><topic>Iron oxides</topic><topic>Morphology</topic><topic>multidisciplinary</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Nitrogen</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>Silicon dioxide</topic><topic>Sulfur</topic><topic>Triazine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kafshdarzadeh, Kosar</creatorcontrib><creatorcontrib>Malmir, Masoume</creatorcontrib><creatorcontrib>Amiri, Zahra</creatorcontrib><creatorcontrib>Heravi, Majid M.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection (Proquest)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database (ProQuest)</collection><collection>Biological Science Database</collection><collection>Publicly Available Content (ProQuest)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kafshdarzadeh, Kosar</au><au>Malmir, Masoume</au><au>Amiri, Zahra</au><au>Heravi, Majid M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic liquid-loaded triazine-based magnetic nanoparticles for promoting multicomponent reaction</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2022-12-23</date><risdate>2022</risdate><volume>12</volume><issue>1</issue><spage>22261</spage><epage>12</epage><pages>22261-12</pages><artnum>22261</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>A novel hybrid magnetic ionic-liquid as a heterogeneous catalyst was synthesized by hybridization of imidazolium based-ionic liquid onto the nitrogen rich magnetic nanocomposite. The resulting catalyst (n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL) has two advantages besides recyclability: (i) high capacity of functional-SO
3
H group with imidazolium-IL cation for promoting symmetric and asymmetric Hantzsch reaction and (ii) easy recovery. Caused by the polymeric and magnetic nature of the n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL, large quantities of acidic groups were bound to the n-Fe
3
O
4
@SiO
2
-TA surface, which reduced the catalyst mass applied to the catalytic reaction. Moreover, superior catalytic performance and outstanding recyclability of n-Fe
3
O
4
@SiO
2
-TA-SO
3
H IL in mild condition make this method a green pathway for manufacture of satisfactory chemicals.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>36564418</pmid><doi>10.1038/s41598-022-26235-6</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Scientific reports, 2022-12, Vol.12 (1), p.22261-12, Article 22261 |
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| language | eng |
| recordid | cdi_doaj_primary_oai_doaj_org_article_ea88c3eaf3f048098d806063302004c6 |
| source | PubMed Central Free; Publicly Available Content (ProQuest); Free Full-Text Journals in Chemistry; Springer Nature - nature.com Journals - Fully Open Access |
| subjects | 639/638/77 639/638/77/884 639/638/77/885 639/638/77/887 Catalysts Chemistry Humanities and Social Sciences Hybridization Ions Iron oxides Morphology multidisciplinary Nanocomposites Nanoparticles Nitrogen Science Science (multidisciplinary) Silicon dioxide Sulfur Triazine |
| title | Ionic liquid-loaded triazine-based magnetic nanoparticles for promoting multicomponent reaction |
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