Effect of Deashing Treatment on Ash Fusion Characteristics of Biochar from Bamboo Shoot Shells

• Published in: Molecules (Basel, Switzerland) Switzerland), 2024-03, Vol.29 (6), p.1400
• Main Authors: Ren, Hao, Gao, Qi, Ni, Liangmeng, Su, Mengfu, Rong, Shaowen, Liu, Shushu, Zhong, Yanhang, Liu, Zhijia
• Format: Article
• Language: English
• Subjects: Alkalies; Amino acids; ash fusion; ash phase transformation; bamboo shoot shells; biochar deashing; Biomass energy; Charcoal - chemistry; Coal Ash; Corrosion; Efficiency; Hydrochloric acid; Metals; Potassium; Silicates; Temperature; Water
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules29061400

To investigate the influence of deashing on fusion characteristics, a combined method of water and acid washing with different sequences (water washing followed by acid washing, and acid washing followed by water washing) was used to treat the biochar of bamboo shoot shells (BBSSs). The results show that deashing decreased the K content of the biochar from 50.3% to 1.08% but increased the Si content from 33.48% to 89.15%. The formation of silicates and aluminosilicates from alkali metal oxides with silicon was an inevitable result of ash phase transformation at the high temperatures used to improve the fusion temperature (>1450 °C). The thermochemical behavior of ash mainly occurs at 1000 °C. The deashing treatment significantly reduced the reaction intensity during the high-temperature process. This significantly increased the thermal stability of the ash. The adjustment of the washing sequence had a slight impact on the chemical compositions, but the differences in ash micromorphology were obvious. Deashing treatments with different washing sequences can significantly improve ash fusion properties effectively and reduce the risk of scaling, slagging, and corrosion. This study provides a new and reasonable strategy for the deashing of biochar to commercially utilize bamboo shoot shell resources.