Poisoning Mechanism Map for Metal Hydride Hydrogen Storage Materials

• Published in: Advanced science 2024-11, Vol.11 (43), p.e2408522-n/a
• Main Authors: Bi, Jiapeng, Zhou, Panpan, Jiang, Wei, Kou, Huaqin, Tang, Tao, Zhang, Yajie, Liu, Yang, Zhou, Qianwen, Yao, Yunxi, Zhang, Yuan, Yang, Mao, Chen, Lixin, Xiao, Xuezhang
• Format: Article
• Language: English
• Subjects: Chemical reactions; Gas absorption; Gases; Hydrogen; hydrogen storage materials; Hydrogenation; hydrogenation kinetics; impurity gas; Isotopes; Kinetics; Poisoning; poisoning mechanisms; rate controlling step
• ISSN: 2198-3844; 2198-3844
• DOI: 10.1002/advs.202408522

The effective utilization of hydrogen storage materials (HSMs) is hindered by impurity gas poisoning, posing a significant challenge for large‐scale applications. This study elucidates the poisoning mechanisms of various impurities gases (CO, CO2, O2, Ar, He, CH4, N2) on ZrCo, Pd, U and LaNi5. Impurities gases are categorized into active and inactive types based on their effecting behaviors and mechanisms on the hydrogenation of HSMs. During the hydrogenation process, active impurities chemically poison the hydrogenation reaction by limiting hydrogen absorption at interface, while inactive impurities physically hinder hydrogenation reaction by impeding hydrogen diffusion in hydrogen‐impurity mixed gas. In situ Scanning Tunneling Microscope clarifies these behaviors, and a novel criterion based on hydrogen spontaneous dissociation energy is introduced to explain and predict impurity–substrate interaction characteristics. The novel findings of this work provide a comprehensive framework for designing long‐lived HSMs with poisoning resistance, guiding the development of more resilient hydrogen storage systems. The poisoning mechanisms of impurity gases on hydrogen storage materials are classified into two basic categories. During hydrogenation, inactive gases cause a minimal blanket effect by physically obstructing H2 diffusion in H2‐impurity mixed gas, while active gases significantly poison materials by chemically limiting H2 absoprtion at interface. This understanding informs targeted strategies for comprehensive anti‐poisoning optimizations.