Anchoring Cu1 species over nanodiamond-graphene for semi-hydrogenation of acetylene

The design of cheap, non-toxic, and earth-abundant transition metal catalysts for selective hydrogenation of alkynes remains a challenge in both industry and academia. Here, we report a new atomically dispersed copper (Cu) catalyst supported on a defective nanodiamond-graphene (ND@G), which exhibits...

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Published in:Nature communications 2019-09, Vol.10 (1), p.1-7, Article 4431
Main Authors: Huang, Fei, Deng, Yuchen, Chen, Yunlei, Cai, Xiangbin, Peng, Mi, Jia, Zhimin, Xie, Jinglin, Xiao, Dequan, Wen, Xiaodong, Wang, Ning, Jiang, Zheng, Liu, Hongyang, Ma, Ding
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119/118
639/638/298
639/638/77
Acetylene
Alkynes
Anchoring
Catalysts
Catalytic converters
Conversion
Copper
Diamonds
Ethylene
Graphene
Humanities and Social Sciences
Hydrogenation
multidisciplinary
Nanostructure
Science
Science (multidisciplinary)
Selectivity
Transition metals
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Jiang, Zheng
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description The design of cheap, non-toxic, and earth-abundant transition metal catalysts for selective hydrogenation of alkynes remains a challenge in both industry and academia. Here, we report a new atomically dispersed copper (Cu) catalyst supported on a defective nanodiamond-graphene (ND@G), which exhibits excellent catalytic performance for the selective conversion of acetylene to ethylene, i.e., with high conversion (95%), high selectivity (98%), and good stability (for more than 60 h). The unique structural feature of the Cu atoms anchored over graphene through Cu-C bonds ensures the effective activation of acetylene and easy desorption of ethylene, which is the key for the outstanding activity and selectivity of the catalyst. It is highly desired to explore cheap, non-toxic transition metals catalysts for semihydrogenation of acetylene. Here, isolated Cu atoms anchored onto a defective nanodiamond-graphene support exhibit robust catalytic performance in acetylene semihydrogenation in comparison with supported Cu clusters.
doi_str_mv 10.1038/s41467-019-12460-7
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subjects 119/118
639/638/298
639/638/77
Acetylene
Alkynes
Anchoring
Catalysts
Catalytic converters
Conversion
Copper
Diamonds
Ethylene
Graphene
Humanities and Social Sciences
Hydrogenation
multidisciplinary
Nanostructure
Science
Science (multidisciplinary)
Selectivity
Transition metals
title Anchoring Cu1 species over nanodiamond-graphene for semi-hydrogenation of acetylene
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