Investigation of the impact of satellite vertical sensitivity on long-term retrieved lower-tropospheric ozone trends

• Published in: Atmospheric chemistry and physics 2024-08, Vol.24 (16), p.9177-9195
• Main Authors: Pope, Richard J, O'Connor, Fiona M, Dalvi, Mohit, Kerridge, Brian J, Siddans, Richard, Latter, Barry G, Barret, Brice, Le Flochmoen, Eric, Boynard, Anne, Chipperfield, Martyn P, Feng, Wuhu, Pimlott, Matilda A, Dhomse, Sandip S, Retscher, Christian, Wespes, Catherine, Rigby, Richard
• Format: Article
• Language: English
• Subjects: Air pollution; Analysis; Atmospheric sounding; Climate change; Climate science; Datasets; Emissions; Infrared interferometers; Interannual variability; Investigations; Lower troposphere; Measurement techniques; Monitoring instruments; Ocean, Atmosphere; Ozone; Ozone monitoring; Ozone profiles; Ozone trends; Radiative transfer; Satellite data; Satellites; Sciences of the Universe; Sensitivity; Spatiotemporal data; Trends; Troposphere; Tropospheric ozone; Uncertainty; Upper troposphere
• ISSN: 1680-7316; 1680-7324
• DOI: 10.5194/acp-24-9177-2024

Ozone is a potent air pollutant in the lower troposphere and an important short-lived climate forcer (SLCF) in the upper troposphere. Studies investigating long-term trends in the tropospheric column ozone (TCO.sub.3) have shown large-scale spatio-temporal inconsistencies. Here, we investigate the long-term trends in lower-tropospheric column ozone (LTCO.sub.3, surface-450 hPa sub-column) by exploiting a synergy of satellite and ozonesonde data sets and an Earth system model (UK's Earth System Model, UKESM) over North America, Europe, and East Asia for the decade 2008-2017. Overall, we typically find small LTCO.sub.3 linear trends with large uncertainty ranges using the Ozone Monitoring Instrument (OMI) and the Infrared Atmospheric Sounding Interferometer (IASI), while model simulations indicate a stable LTCO.sub.3 tendency. The satellite a priori data sets show negligible trends, indicating that any year-to-year changes in the spatio-temporal sampling of these satellite data sets over the period concerned have not artificially influenced their LTCO.sub.3 temporal evolution. The application of the satellite averaging kernels (AKs) to the UKESM simulated ozone profiles, accounting for the satellite vertical sensitivity and allowing for like-for-like comparisons, has a limited impact on the modelled LTCO.sub.3 tendency in most cases. While, in relative terms, this is more substantial (e.g. on the order of 100 %), the absolute magnitudes of the model trends show negligible change. However, as the model has a near-zero tendency, artificial trends were imposed on the model time series (i.e. LTCO.sub.3 values rearranged from smallest to largest) to test the influence of the AKs, but simulated LTCO.sub.3 trends remained small. Therefore, the LTCO.sub.3 tendencies between 2008 and 2017 in northern-hemispheric regions are likely to be small, with large uncertainties, and it is difficult to detect any small underlying linear trends due to interannual variability or other factors which require further investigation (e.g. the radiative transfer scheme (RTS) used and/or the inputs (e.g. meteorological fields) used in the RTS).