Aquabis[ N ′-(1,3-dithiolan-2-ylidene)-2-hydroxybenzohydrazidato(0.5−)-κ 2 N ′, O ]sodium(I)

The title compound, [Na(C 10 H 9.5 N 2 O 2 S 2 ) 2 (H 2 O)], is a molecular sodium complex with N ′-(1,3-dithiolan-2-yl)-2-hydroxybenzohydrazide ligands with the negative charge spread evenly over both, and a water molecule. The Na I ion coordination is distorted trigonal–bipyramidal, formed by two...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-06, Vol.68 (6), p.m827-m828
Main Authors: Bouchameni, Chahra, Beghidja, Chahrazed, Beghidja, Adel, Boutebdja, Mehdi
Format: Article
Language:English
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Summary:The title compound, [Na(C 10 H 9.5 N 2 O 2 S 2 ) 2 (H 2 O)], is a molecular sodium complex with N ′-(1,3-dithiolan-2-yl)-2-hydroxybenzohydrazide ligands with the negative charge spread evenly over both, and a water molecule. The Na I ion coordination is distorted trigonal–bipyramidal, formed by two N and three O atoms, with the Na I ion lying on a twofold rotation axis. Intramolecular N—H...O hydrogen bonds occur. Molecules pack as discrete units and the crystal packing is stabilized by strong O—H...O hydrogen bonds, which give rise to chains along [010]; the chains are interlinked by strong O—H...O hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812023239