Photophysical and Electrochemical Studies of Multinuclear Complexes of Iron(II) with Acetate and Extended Conjugated N-Donor Ligands

• Published in: TheScientificWorld 2015, Vol.2015 (2015), p.1-8
• Main Authors: Azil, Afiq, Roslan, Muhamad Faris, Marlina, Anita, Mohd Said, Suhana, Abdullah, N., Nordin, Abdul Rahman
• Format: Article
• Language: English
• Subjects: Absorption; Acetates; Electrochemical analysis; Electrochemistry; Electrodes; Fluorescence; Iron; Iron compounds; Lifetime; Ligands; Methods; Properties; Redox potential; Solar cells
• ISSN: 2356-6140; 1537-744X; 1537-744X
• DOI: 10.1155/2015/860537

A dimeric iron(II) complex, trans-[Fe2(CH3COO)4(L1)2] (1), and a trinuclear iron(II) complex, [Fe3(CH3COO)4(H2O)4(L2)] (2), were studied as potential dye-sensitised solar cell materials. The structures of both complexes were deduced by a combination of instrumental analyses and molecular modelling. Variable-temperature magnetic susceptibility data suggested that 1 was made up of 56.8% high-spin (HS) and 43.2% low-spin (LS) Fe(II) atoms at 294 K and has a moderate antiferromagnetic interaction (J = −81.2 cm−1) between the two Fe(II) centres, while 2 was made up of 27.7% HS and 72.3% LS Fe(II) atoms at 300 K. The optical band gaps (Eo) for 1 were 1.9 eV (from absorption spectrum) and 2.2 eV (from fluorescence spectrum), electrochemical bandgap (Ee) was 0.83 eV, excited state lifetime (τ) was 0.67 ns, and formal redox potential (E′(FeIII/FeII)) was +0.63 V. The corresponding values for 2 were 3.5 eV (from absorption spectrum), 1.8 eV (from fluorescence spectrum), 0.69 eV, 2.8 ns, and +0.41 V.