Tetrakis[μ-1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ 2 N : N ′]trisilver(I) tris(hexafluoridophosphate)

In the title compound, [Ag3(C12H12N2O2)4](PF6)3, one AgI ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetrahedral geometry and the other AgI ion is coordinated by two N atoms from two L ligands...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-09, Vol.68 (9), p.m1170-m1170
Main Authors: Yeh, Chun-Wei, Ho, Yuh-Wen, Lee, Hsun-Tsing, Wang, Ju-Chun, Suen, Maw-Cherng
Format: Article
Language:English
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Summary:In the title compound, [Ag3(C12H12N2O2)4](PF6)3, one AgI ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetrahedral geometry and the other AgI ion is coordinated by two N atoms from two L ligands in a bent arrangement [N—Ag—N = 169.03 (17)°]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent AgI ions, forming a trinuclear complex. One of the PF6− anions is half-occupied, with the P atom located on a twofold rotation axis. The PF6− anions link the complex molecules via Ag...F interactions [2.80 (2) and 2.85 (2) Å] into a polymeric chain along [100].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812034721