Probing Iceland's dust-emitting sediments: particle size distribution, mineralogy, cohesion, Fe mode of occurrence, and reflectance spectra signatures

• Published in: Atmospheric chemistry and physics 2024-06, Vol.24 (11), p.6883-6910
• Main Authors: González-Romero, Adolfo, González-Flórez, Cristina, Panta, Agnesh, Yus-Díez, Jesús, Córdoba, Patricia, Alastuey, Andres, Moreno, Natalia, Kandler, Konrad, Klose, Martina, Clark, Roger N, Ehlmann, Bethany L, Greenberger, Rebecca N, Keebler, Abigail M, Brodrick, Phil, Green, Robert O, Querol, Xavier, Pérez García-Pando, Carlos
• Format: Article
• Language: English
• Subjects: Aggregation; Analysis; Arid regions; Arid zones; Atmospheric particulates; Chemical properties; Chemicophysical properties; Climate change; Cohesion; Concretions; Crusts; Dust; Dust effects; Emissions; Entrainment; Feldspars; Floods; Glaciers; Goethite; Haematite; Hematite; Infrared spectra; Investigations; Iron; Iron content; Latitude; Magnetite; Mineralogy; Near infrared radiation; Outdoor air quality; Particle size; Particle size distribution; Physicochemical processes; Physicochemical properties; Reflectance; Saltation; Sediment; Sediment samples; Sediments; Sediments (Geology); Silicates; Size distribution; Spectra; Spectral emittance
• ISSN: 1680-7316; 1680-7324
• DOI: 10.5194/acp-24-6883-2024

Characterising the physico-chemical properties of dust-emitting sediments in arid regions is fundamental to understanding the effects of dust on climate and ecosystems. However, knowledge regarding high-latitude dust (HLD) remains limited. This study focuses on analysing the particle size distribution (PSD), mineralogy, cohesion, iron (Fe) mode of occurrence, and visible-near infrared (VNIR) reflectance spectra of dust-emitting sediments from dust hotspots in Iceland (HLD region). Extensive analysis was conducted on samples of top sediments, sediments, and aeolian ripples collected from seven dust sources, with particular emphasis on the Jökulsá basin, encompassing the desert of Dyngjunsandur. Both fully and minimally dispersed PSDs and their respective mass median particle diameters revealed remarkable similarities (56 ± 69 and 55 ± 62 µm, respectively). Mineralogical analyses indicated the prevalence of amorphous phases (68 ± 26 %), feldspars (17 ± 13 %), and pyroxenes (9.3 ± 7.2 %), consistent with thorough analyses of VNIR reflectance spectra. The Fe content reached 9.5 ± 0.40 wt %, predominantly within silicate structures (80 ± 6.3 %), complemented by magnetite (16 ± 5.5 %), hematite/goethite (4.5 ± 2.7 %), and readily exchangeable Fe ions or Fe nano-oxides (1.6 ± 0.63 %). Icelandic top sediments exhibited coarser PSDs compared to the high dust-emitting crusts from mid-latitude arid regions, distinctive mineralogy, and a 3-fold bulk Fe content, with a significant presence of magnetite. The congruence between fully and minimally dispersed PSDs underscores reduced particle aggregation and cohesion of Icelandic top sediments, suggesting that aerodynamic entrainment of dust could also play a role upon emission in this region, alongside saltation bombardment. The extensive analysis in Dyngjusandur enabled the development of a conceptual model to encapsulate Iceland's rapidly evolving high dust-emitting environments.