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Preparation of Nanoscale Urushiol/PAN Films to Evaluate Their Acid Resistance and Protection of Functional PVP Films

Different amounts of urushiol were added to a fixed amount of polyacrylonitrile (PAN) to make nanoscale urushiol/PAN films by the electrospinning method. Electrospinning solutions were prepared by using dimethylformamide (DMF) as the solvent. Nanoscale urushiol/PAN films and conductive Poly(3,4-ethy...

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Bibliographic Details
Published in:Nanomaterials (Basel, Switzerland) Switzerland), 2021-04, Vol.11 (4), p.957
Main Authors: Wu, Kunlin, Shiu, Bing-Chiuan, Zhang, Ding, Shen, Zhenhao, Liu, Minghua, Lin, Qi
Format: Article
Language:English
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Summary:Different amounts of urushiol were added to a fixed amount of polyacrylonitrile (PAN) to make nanoscale urushiol/PAN films by the electrospinning method. Electrospinning solutions were prepared by using dimethylformamide (DMF) as the solvent. Nanoscale urushiol/PAN films and conductive Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)/polyvinyl pyrrolidone (PVP) films were prepared by electrospinning. In order to prepare an electrospun sandwich nanoscale film, urushiol/PAN films were deposited as both the top and bottom layers and PEDOT:PSS/PVP film as the inner layer. When the PAN to urushiol ratio was 7:5, the fiber diameter ranged between 150 nm and 200 nm. The single-layer urushiol/PAN film could not be etched after being immersed into 60%, 80%, and 100% sulfuric acid (H SO ) for 30 min, which indicated the improved acid resistance of the PAN film. The urushiol/PAN film was used to fabricate the sandwich nanoscale films. When the sandwich film was immersed into 80% and 100% H SO solutions for 30 min, the structure remained intact, and the conductive PVP film retained its original properties. Thus, the working environment tolerability of the functional PVP film was increased.
ISSN:2079-4991
2079-4991
DOI:10.3390/nano11040957