A Dual-Channel MoS2-Based Selective Gas Sensor for Volatile Organic Compounds

• Published in: Nanomaterials (Basel, Switzerland) Switzerland), 2024-04, Vol.14 (7), p.633
• Main Authors: Kuş, Esra, Altındemir, Gülay, Bostan, Yusuf Kerem, Taşaltın, Cihat, Erol, Ayse, Wang, Yue, Sarcan, Fahrettin
• Format: Article
• Language: English
• Subjects: 2D materials; Acetone; Ammonia; Chalcogenides; Contact angle; Electrons; Ethanol; Fabrication; Gas sensor; Gas sensors; Gases; Glass substrates; Graphene; Molybdenum; Molybdenum disulfide; MoS2; Nanoparticles; Organic compounds; Physics; Polymethyl methacrylate; Selectivity; Semiconductors; Sensitivity enhancement; Sensors; Spectrum analysis; Thin films; TMDs; Toluene; Transition metal compounds; Two dimensional materials; VOC; VOCs; Volatile compounds; Volatile organic compounds; Zinc oxides
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano14070633

Significant progress has been made in two-dimensional material-based sensing devices over the past decade. Organic vapor sensors, particularly those using graphene and transition metal dichalcogenides as key components, have demonstrated excellent sensitivity. These sensors are highly active because all the atoms in the ultra-thin layers are exposed to volatile compounds. However, their selectivity needs improvement. We propose a novel gas-sensing device that addresses this challenge. It consists of two side-by-side sensors fabricated from the same active material, few-layer molybdenum disulfide (MoS₂), for detecting volatile organic compounds like alcohol, acetone, and toluene. To create a dual-channel sensor, we introduce a simple step into the conventional 2D material sensor fabrication process. This step involves treating one-half of the few-layer MoS₂ using ultraviolet–ozone (UV-O3) treatment. The responses of pristine few-layer MoS₂ sensors to 3000 ppm of ethanol, acetone, and toluene gases are 18%, 3.5%, and 49%, respectively. The UV-O3-treated few-layer MoS₂-based sensors show responses of 13.4%, 3.1%, and 6.7%, respectively. This dual-channel sensing device demonstrates a 7-fold improvement in selectivity for toluene gas against ethanol and acetone. Our work sheds light on understanding surface processes and interaction mechanisms at the interface between transition metal dichalcogenides and volatile organic compounds, leading to enhanced sensitivity and selectivity.